Alkane functionalization / Pombeiro, Armando, J. L.

Public ISBD Titre : Alkane functionalization Type de document : texte imprimé Auteurs : Pombeiro, Armando, J. L., Éditeur scientifique ; Guedes da Silva, M. Fatima C., Éditeur scientifique Editeur : New York : Wiley Année de publication : 2019 Importance : xxxiv, 614 p. ISBN/ISSN/EAN : 978-1-119-37880-8 Langues : Français (fre) Tags : OXYDATIONS Résumé : The authors describe the various modes of interaction of alkanes with metal centres and examine theoxidative alkane functionalization upon C-O bond formation. They address the many types of mechanisms, discuss typical catalytic systems and highlight the strategies inspired by biological catalytic systems. The book also describes alkane functionalization upon C-heteroatom bond formation as well as oxidative and non-oxidative approaches. In addition, the book explores non-transition metal catalysts and metal-free catalytic systems and presents selected types of functionalization of sp3 C-H bonds pertaining to substrates other than alkanes. Note de contenu : "* Alkane Functionalization: Introduction And Overview * Activation and oxidative functionalization of alkanes with noble-metal catalysts: Molecular mechanisms * Alkane-oxidizing systems based on metal complexes. Radical versus non-radical mechanisms * Reactions of alkyl radicals in aqueous solutions * C–H bond oxidation with transition metal based carbene complexes * Alkane oxidation with C-scorpionate metal complexes * Alkane oxidation with multinuclear heterometallic catalysts * Oxidative functionalization of methane on heterogeneous catalysts * Gas-phase oxidation of alkanes * Recent developments of bio-inspired approaches to functionalization of light alkanes * Regioselectivity of non-heme iron catalysts for C-H activation * Imine-based Iron and Manganese Complexes as Catalysts for Alkane Functionalization * Alkane oxidation with biologically inspired nonheme iron catalysts based in the triazacyclononane ligand scaffold * The nature of high-valent oxometal intermediates of iron-aminopyridine mediated oxidations * Selective Oxidation of Alkanes by Metallo-Monooxygenases and their Nano-Biomimetics * Alkane oxidation with vanadium and copper catalysts * Catalytic borylation of methane: combining computational and high-throughput screening approaches to discover a new catalyst * Alkane carbonylation and carbene insertion reactions * Catalytic alkane amidation and related reactions * Oxidative and non-oxidative routes to alkane dehydrogenation * Dehydrogenation of alkanes using molecular catalysts * Non-transition metal catalyzed oxidation of alkanes with peroxides * Metal-free functionalization of alkanes * Alkane functionalization under unconventional conditions: in ionic liquid, in supercritical co2 and microwave assisted * Alkane related C-H bond activation and functionalization of aliphatic amines". Cote : B-D202 Num_Inv : 636 Localisation : LCC (SdS) Alkane functionalization [texte imprimé] / Pombeiro, Armando, J. L., Éditeur scientifique ; Guedes da Silva, M. Fatima C., Éditeur scientifique . - New York : Wiley, 2019 . - xxxiv, 614 p. ISBN : 978-1-119-37880-8 Langues : Français (fre) Tags : OXYDATIONS Résumé : The authors describe the various modes of interaction of alkanes with metal centres and examine theoxidative alkane functionalization upon C-O bond formation. They address the many types of mechanisms, discuss typical catalytic systems and highlight the strategies inspired by biological catalytic systems. The book also describes alkane functionalization upon C-heteroatom bond formation as well as oxidative and non-oxidative approaches. In addition, the book explores non-transition metal catalysts and metal-free catalytic systems and presents selected types of functionalization of sp3 C-H bonds pertaining to substrates other than alkanes. Note de contenu : "* Alkane Functionalization: Introduction And Overview * Activation and oxidative functionalization of alkanes with noble-metal catalysts: Molecular mechanisms * Alkane-oxidizing systems based on metal complexes. Radical versus non-radical mechanisms * Reactions of alkyl radicals in aqueous solutions * C–H bond oxidation with transition metal based carbene complexes * Alkane oxidation with C-scorpionate metal complexes * Alkane oxidation with multinuclear heterometallic catalysts * Oxidative functionalization of methane on heterogeneous catalysts * Gas-phase oxidation of alkanes * Recent developments of bio-inspired approaches to functionalization of light alkanes * Regioselectivity of non-heme iron catalysts for C-H activation * Imine-based Iron and Manganese Complexes as Catalysts for Alkane Functionalization * Alkane oxidation with biologically inspired nonheme iron catalysts based in the triazacyclononane ligand scaffold * The nature of high-valent oxometal intermediates of iron-aminopyridine mediated oxidations * Selective Oxidation of Alkanes by Metallo-Monooxygenases and their Nano-Biomimetics * Alkane oxidation with vanadium and copper catalysts * Catalytic borylation of methane: combining computational and high-throughput screening approaches to discover a new catalyst * Alkane carbonylation and carbene insertion reactions * Catalytic alkane amidation and related reactions * Oxidative and non-oxidative routes to alkane dehydrogenation * Dehydrogenation of alkanes using molecular catalysts * Non-transition metal catalyzed oxidation of alkanes with peroxides * Metal-free functionalization of alkanes * Alkane functionalization under unconventional conditions: in ionic liquid, in supercritical co2 and microwave assisted * Alkane related C-H bond activation and functionalization of aliphatic amines". Cote : B-D202 Num_Inv : 636 Localisation : LCC (SdS)

Exemplaires(1)

Code-barres	Cote	Support	Localisation	Section	Disponibilité
636	B-D202	Texte imprimé	Bibliothèque	Livre	Disponible

Noncovalent interactions in catalysis / Mahmudov, Kamran T.

Public ISBD Titre : Noncovalent interactions in catalysis Type de document : texte imprimé Auteurs : Mahmudov, Kamran T., Éditeur scientifique ; Kopylovich, Maximilian N., Éditeur scientifique ; Guedes da Silva, M. Fatima C., Éditeur scientifique ; Pombeiro, Armando, J. L., Éditeur scientifique Editeur : Cambridge : Royal Society of Chemistry Année de publication : 2019 Collection : Catalysis Series Importance : xxi, 653 p. ISBN/ISSN/EAN : 978-1-78801-468-7 Note générale : "Catalysis is a major area of scientific research covering numerous fields of chemistry, and is a key factor in tackling many of the scientific challenges faced today, such as renewable energy systems and environmental protection. The books in this series provide an accessible reference for postgraduates, academics and industrialists working in this exciting field. The books cover both the research developments and applications of catalysis, across academia and industry." Langues : Anglais (eng) Catégories : Catalyse Tags : CATALYSIS  CHEMICAL BONDS  HYDROGEN BONDING Index. décimale : B-E Résumé : "Noncovalent interactions often provide the spine of biomolecular and material structures, and can therefore play a key role in biological and catalytic processes. Selectivity in chemical reactions, particularly in catalytic processes, is often an orchestral action of various noncovalent interactions occurring in intermediates and transition states. Although the role of hydrogen bonding is well explored in catalysis, the other types of weak interactions, namely cation–?, anion–?, ?–? stacking, pseudo-agostic, halogen, chalcogen, pnictogen, tetrel and icosagen bonds, must also be considered. Naturally, the chemo-, regio- or stereoselectivity of a reaction depends on the stability of such noncovalent-interaction-supported species in catalytic systems. Therefore, an in-depth understanding of these weak interactions may be the key to designing new catalytic materials. Providing an overview of the role of these different types of noncovalent interactions in both homogenous and heterogeneous catalysis, this book is a valuable resource for synthetic chemists who are interested in exploring and further developing noncovalent-interaction-assisted synthesis and catalysis." Note de contenu : "* Noncovalent interactions in C–H Bond functionalization * Importance of C–H hydrogen bonding in asymmetric catalysis * Catalysis by networks of cooperative hydrogen bonds * Secondary (agostic Si–H/electrostatic C–F) interactions in alkaline earth-based catalysts * Anion–? catalysis * Onium ion-assisted organic reactions through cation–? interactions * The role of noncovalent interactions in the efficiency of dendrimers in catalysis * Noncovalent interactions in hydrogenation and hydroformylation * Soft forces in organic synthesis by C–N coupling reactions * Noncovalent interactions in the design of chiral Brønsted acid catalysts * Noncovalent interactions in the nitroaldol (Henry) reaction * Noncovalent interactions in asymmetric reactions catalysed by chiral phosphoric acids * Baeyer–Villiger oxidation promoted by noncovalent interactions * Noncovalent interactionassisted redox catalysis in reductive dehalogenation * Noncovalent immobilization of catalysts on electrode surfaces * Noncovalent interactions in ionic liquids * Ionic liquid effect in catalysed multicomponent reactions * Noncovalent interactions in olefin polymerization catalysis promoted by transition metals * Influence of noncovalent interactions in catalytic ring-opening polymerization processes * Cavity effects in metal–organic frameworks * Cavity effects in metal–organic frameworks in CO2 capture and conversion * Hybrids of metal–organic frameworks as organized supramolecular nano-reactors * The Nature of hydrogen bonding in adsorbed CO2 and H2O on solid amines in CO2 capture * Noncovalent interactions of biogenic impurities with transition metal catalyst surfaces * Mechanochemical activation and catalysis * Role of ion pairing in the mechanisms of Au(i)-catalysed reactions: theory and experiment * Noncovalent interactions in key metal-centred catalytic intermediates: Structure - electronic relationship * Noncovalent interactions in biocatalysis - A theoretical perspective * Analysis of reactivity from the noncovalent interactions perspective". Cote : B-E096 (SdS) Num_Inv : 634 Localisation : Bibliothèque Noncovalent interactions in catalysis [texte imprimé] / Mahmudov, Kamran T., Éditeur scientifique ; Kopylovich, Maximilian N., Éditeur scientifique ; Guedes da Silva, M. Fatima C., Éditeur scientifique ; Pombeiro, Armando, J. L., Éditeur scientifique . - Cambridge : Royal Society of Chemistry, 2019 . - xxi, 653 p.. - (Catalysis Series) . ISBN : 978-1-78801-468-7 "Catalysis is a major area of scientific research covering numerous fields of chemistry, and is a key factor in tackling many of the scientific challenges faced today, such as renewable energy systems and environmental protection. The books in this series provide an accessible reference for postgraduates, academics and industrialists working in this exciting field. The books cover both the research developments and applications of catalysis, across academia and industry." Langues : Anglais (eng) Catégories : Catalyse Tags : CATALYSIS  CHEMICAL BONDS  HYDROGEN BONDING Index. décimale : B-E Résumé : "Noncovalent interactions often provide the spine of biomolecular and material structures, and can therefore play a key role in biological and catalytic processes. Selectivity in chemical reactions, particularly in catalytic processes, is often an orchestral action of various noncovalent interactions occurring in intermediates and transition states. Although the role of hydrogen bonding is well explored in catalysis, the other types of weak interactions, namely cation–?, anion–?, ?–? stacking, pseudo-agostic, halogen, chalcogen, pnictogen, tetrel and icosagen bonds, must also be considered. Naturally, the chemo-, regio- or stereoselectivity of a reaction depends on the stability of such noncovalent-interaction-supported species in catalytic systems. Therefore, an in-depth understanding of these weak interactions may be the key to designing new catalytic materials. Providing an overview of the role of these different types of noncovalent interactions in both homogenous and heterogeneous catalysis, this book is a valuable resource for synthetic chemists who are interested in exploring and further developing noncovalent-interaction-assisted synthesis and catalysis." Note de contenu : "* Noncovalent interactions in C–H Bond functionalization * Importance of C–H hydrogen bonding in asymmetric catalysis * Catalysis by networks of cooperative hydrogen bonds * Secondary (agostic Si–H/electrostatic C–F) interactions in alkaline earth-based catalysts * Anion–? catalysis * Onium ion-assisted organic reactions through cation–? interactions * The role of noncovalent interactions in the efficiency of dendrimers in catalysis * Noncovalent interactions in hydrogenation and hydroformylation * Soft forces in organic synthesis by C–N coupling reactions * Noncovalent interactions in the design of chiral Brønsted acid catalysts * Noncovalent interactions in the nitroaldol (Henry) reaction * Noncovalent interactions in asymmetric reactions catalysed by chiral phosphoric acids * Baeyer–Villiger oxidation promoted by noncovalent interactions * Noncovalent interactionassisted redox catalysis in reductive dehalogenation * Noncovalent immobilization of catalysts on electrode surfaces * Noncovalent interactions in ionic liquids * Ionic liquid effect in catalysed multicomponent reactions * Noncovalent interactions in olefin polymerization catalysis promoted by transition metals * Influence of noncovalent interactions in catalytic ring-opening polymerization processes * Cavity effects in metal–organic frameworks * Cavity effects in metal–organic frameworks in CO2 capture and conversion * Hybrids of metal–organic frameworks as organized supramolecular nano-reactors * The Nature of hydrogen bonding in adsorbed CO2 and H2O on solid amines in CO2 capture * Noncovalent interactions of biogenic impurities with transition metal catalyst surfaces * Mechanochemical activation and catalysis * Role of ion pairing in the mechanisms of Au(i)-catalysed reactions: theory and experiment * Noncovalent interactions in key metal-centred catalytic intermediates: Structure - electronic relationship * Noncovalent interactions in biocatalysis - A theoretical perspective * Analysis of reactivity from the noncovalent interactions perspective". Cote : B-E096 (SdS) Num_Inv : 634 Localisation : Bibliothèque

Exemplaires(2)

Code-barres	Cote	Support	Localisation	Section	Disponibilité
634	B-E096	Texte imprimé	Bibliothèque	Livre	Disponible
3667	B-E096	Texte imprimé	Bibliothèque	Livre	Disponible

---

1 (1 - 2 / 2) Par page : 25 50 100 200