The nature of the chemical bond / Bruns, Carson J.

Public ISBD Titre : The nature of the chemical bond : From molecules to machines Type de document : texte imprimé Auteurs : Bruns, Carson J., Auteur ; Stoddart, J. Fraser, Auteur Editeur : Chichester : Wiley Année de publication : 2017 Importance : xx, 761 p. ISBN/ISSN/EAN : 978-1-119-04400-0 Langues : Anglais (eng) Catégories : Chimie de coordination, Chimie organométallique, Métaux de transition Tags : CHEMICAL BONDS Index. décimale : B-D Résumé : The Nature of the Mechanical Bond is a comprehensive review of much of the contemporary literature on the mechanical bond, accessible to newcomers and veterans alike. Topics covered include: * Supramolecular, covalent, and statistical approaches to the formation of entanglements that underpin mechanical bonds in molecules and macromolecules * Kinetically and thermodynamically controlled strategies for synthesizing mechanomolecules * Chemical topology, molecular architectures, polymers, crystals, and materials with mechanical bonds * The stereochemistry of the mechanical bond (mechanostereochemistry), including the novel types of dynamic and static isomerism and chirality that emerge in mechanomolecules * Artificial molecular switches and machines based on the large-amplitude translational and rotational motions expressed by suitably designed catenanes and rotaxanes. Note de contenu : "* Part 1 Introducing Mechanical Bonds *1 An Introduction to the Mechanical Bond * 1.1 The Ubiquity of the Mechanical Bond * 1.2 Representing Molecular Mechanical Bonds * 1.3 Aesthetics of Mechanical Bonds * 1.4 Evolution of Mechanostereochemistry * Part 2 Making Mechanical Bonds * 2 The Fundamentals of Making Mechanical Bonds * 2.1 Statistical Synthesis * 2.2 Directed Synthesis * 2.3 Template-Directed Synthesis * 2.4 Active Template Synthesis * 3 Making Mechanical Bonds Under Thermodynamic Control * 3.1 Slippage * 3.2 Self-Assembling Metallo-Organic MIMs * 3.3 Mechanical Bond Formation by Condensation * 3.4 Mechanical Bond Formation by Olefin Metathesis * 3.5 Mechanical Bond Formation by Reversible Nucleophilic Reactions * 3.6 Surface-Mounted MIMs * Part 3 Cultivating Mechanical Bonds * 4 Molecular Topologies and Architectures with Mechanical Bonds * 4.1 Catenane Topologies * 4.2 Rotaxane Architectures * 4.3 Other Architectures with Mechanical Bonds * 5 The Stereochemistry of the Mechanical Bond * 5.1 Dynamic Mechanostereoisomerism * 5.2 Static Mechanostereoisomerism * 6 Molecular Switches and Machines with Mechanical Bonds * 6.1 Redox-Driven Switches * 6.2 Photo-Driven Switches * 6.3 Acid/Base-Driven Switches * 6.4 Cation-Triggered Switches * 6.5 Anion-Triggered Switches * 6.6 Switches Driven by Molecular Recognition * 6.7 Switches Driven by Covalent Reactions * 6.8 Solvent-Driven Switches * 6.9 Thermally Driven Switches * 6.10 Pressure-Driven Switches * 6.11 Switches Driven by Electric Fields * 6.12 Switches Driven by Mechanical Force * 6.13 Beyond Translation and Circumrotation * 6.14 Condensed-Phase Switching * 6.15 Mechanomolecular Motors and Machines". Cote : B-D201 Num_Inv : 635 Localisation : LCC (SdS) The nature of the chemical bond : From molecules to machines [texte imprimé] / Bruns, Carson J., Auteur ; Stoddart, J. Fraser, Auteur . - Chichester : Wiley, 2017 . - xx, 761 p. ISBN : 978-1-119-04400-0 Langues : Anglais (eng) Catégories : Chimie de coordination, Chimie organométallique, Métaux de transition Tags : CHEMICAL BONDS Index. décimale : B-D Résumé : The Nature of the Mechanical Bond is a comprehensive review of much of the contemporary literature on the mechanical bond, accessible to newcomers and veterans alike. Topics covered include: * Supramolecular, covalent, and statistical approaches to the formation of entanglements that underpin mechanical bonds in molecules and macromolecules * Kinetically and thermodynamically controlled strategies for synthesizing mechanomolecules * Chemical topology, molecular architectures, polymers, crystals, and materials with mechanical bonds * The stereochemistry of the mechanical bond (mechanostereochemistry), including the novel types of dynamic and static isomerism and chirality that emerge in mechanomolecules * Artificial molecular switches and machines based on the large-amplitude translational and rotational motions expressed by suitably designed catenanes and rotaxanes. Note de contenu : "* Part 1 Introducing Mechanical Bonds *1 An Introduction to the Mechanical Bond * 1.1 The Ubiquity of the Mechanical Bond * 1.2 Representing Molecular Mechanical Bonds * 1.3 Aesthetics of Mechanical Bonds * 1.4 Evolution of Mechanostereochemistry * Part 2 Making Mechanical Bonds * 2 The Fundamentals of Making Mechanical Bonds * 2.1 Statistical Synthesis * 2.2 Directed Synthesis * 2.3 Template-Directed Synthesis * 2.4 Active Template Synthesis * 3 Making Mechanical Bonds Under Thermodynamic Control * 3.1 Slippage * 3.2 Self-Assembling Metallo-Organic MIMs * 3.3 Mechanical Bond Formation by Condensation * 3.4 Mechanical Bond Formation by Olefin Metathesis * 3.5 Mechanical Bond Formation by Reversible Nucleophilic Reactions * 3.6 Surface-Mounted MIMs * Part 3 Cultivating Mechanical Bonds * 4 Molecular Topologies and Architectures with Mechanical Bonds * 4.1 Catenane Topologies * 4.2 Rotaxane Architectures * 4.3 Other Architectures with Mechanical Bonds * 5 The Stereochemistry of the Mechanical Bond * 5.1 Dynamic Mechanostereoisomerism * 5.2 Static Mechanostereoisomerism * 6 Molecular Switches and Machines with Mechanical Bonds * 6.1 Redox-Driven Switches * 6.2 Photo-Driven Switches * 6.3 Acid/Base-Driven Switches * 6.4 Cation-Triggered Switches * 6.5 Anion-Triggered Switches * 6.6 Switches Driven by Molecular Recognition * 6.7 Switches Driven by Covalent Reactions * 6.8 Solvent-Driven Switches * 6.9 Thermally Driven Switches * 6.10 Pressure-Driven Switches * 6.11 Switches Driven by Electric Fields * 6.12 Switches Driven by Mechanical Force * 6.13 Beyond Translation and Circumrotation * 6.14 Condensed-Phase Switching * 6.15 Mechanomolecular Motors and Machines". Cote : B-D201 Num_Inv : 635 Localisation : LCC (SdS)

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635	B-D201	Texte imprimé	Bibliothèque	Livre	Disponible

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