Titre :	Reaction mechanisms of inorganic and organometallic systems
Type de document :	texte imprimé
Auteurs :	Robert B. Jordan
Editeur :	Oxford : Oxford University Press
Année de publication :	1991
Importance :	282 p.
ISBN/ISSN/EAN :	978-0-19-506945-7
Langues :	Anglais (eng)
Catégories :	Chimie de coordination, Chimie organométallique, Métaux de transition
Tags :	CHEMICAL REACTIONS  ORGANOMETALLIC COMPOUNDS  INORGANIC COMPOUNDS
Index. décimale :	B-D
Résumé :	"Introductory chapters concentrate on the collection and interpretation of kinetic data. The chapter on substitution reactions begins with the Langford and Gray classification system and focuses on a sensible approach to mechanistic discussions. Current experimental and theoretical information on solvent exchange reactions is emphasized for substitution on labile systems. Standard stereochemical change processes are discussed, along with a simplified approach to symmetry rules for fluxional organometallic systems. The area of organometallic reactions attempts to bring together and generalize the current work on a variety of common reactions in this area, including C-H activation and a selection of catalytic processes. Electron transfer reactions are discussed in terms of current modifications of Marcus' theory and ideas about bridging ligand effects, including intravalence electron transfer. In inorganic photochemistry, the general factors affecting quantum yields are discussed, with applications to cobalt (III), chromium (III) and rhodium (III) systems, along with flash photolysis and matrix isolation studies in organometallic photochemistry. Selected bioinorganic systems are discussed in detail."
Cote :	B-D163 (SdS)
Num_Inv :	2673

Reaction mechanisms of inorganic and organometallic systems [texte imprimé] / Robert B. Jordan . - Oxford : Oxford University Press, 1991 . - 282 p.
ISBN : 978-0-19-506945-7
Langues : Anglais (eng)

Catégories :	Chimie de coordination, Chimie organométallique, Métaux de transition
Tags :	CHEMICAL REACTIONS  ORGANOMETALLIC COMPOUNDS  INORGANIC COMPOUNDS
Index. décimale :	B-D
Résumé :	"Introductory chapters concentrate on the collection and interpretation of kinetic data. The chapter on substitution reactions begins with the Langford and Gray classification system and focuses on a sensible approach to mechanistic discussions. Current experimental and theoretical information on solvent exchange reactions is emphasized for substitution on labile systems. Standard stereochemical change processes are discussed, along with a simplified approach to symmetry rules for fluxional organometallic systems. The area of organometallic reactions attempts to bring together and generalize the current work on a variety of common reactions in this area, including C-H activation and a selection of catalytic processes. Electron transfer reactions are discussed in terms of current modifications of Marcus' theory and ideas about bridging ligand effects, including intravalence electron transfer. In inorganic photochemistry, the general factors affecting quantum yields are discussed, with applications to cobalt (III), chromium (III) and rhodium (III) systems, along with flash photolysis and matrix isolation studies in organometallic photochemistry. Selected bioinorganic systems are discussed in detail."
Cote :	B-D163 (SdS)
Num_Inv :	2673