Titre :	Topics in Organometallic Chemistry. Vol.68 : Metal-Ligand Co-operativity : Catalysis and the pincer-metal platform
Type de document :	texte imprimé
Auteurs :	Gerard van Koten, Éditeur scientifique ; Kirchner, Karl, Éditeur scientifique ; Moret, Marc-Etienne, Auteur
Editeur :	Berlin, Heidelberg : Springer
Année de publication :	2021
Collection :	Topics in Organometallic Chemistry, ISSN 1436-6002 num. 68
Importance :	x, 449 p.
ISBN/ISSN/EAN :	978-3-030-68915-5
Note générale :	The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal.
Langues :	Anglais (eng)
Index. décimale :	EXCLU Ouvrages interdits de prêt
Résumé :	This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of significant recent developments in the area of metal-ligand cooperativity, with a focus on pincer architectures. The various contributions highlight the widespread impact of M–L co-operativity phenomena on modern organometallic chemistry and catalyst development. The development of efficient and selective catalytic transformations relies on the understanding and fine control of the various elementary reactions that constitutes a catalytic cycle. Co-operative ligands, which actively participate in bond making and bond breaking together to the metal they support, open up new avenues in this area. In particular, buttressing a weak or reactive metal-ligand bond by flanking coordinating arms in a pincer ligand design is proving a versatile strategy to access robust metal complexes that exhibit unusual and selective reactivity patterns.
Note de contenu :	"* Recent Advances in the Applications of Metal-Ligand Cooperation via Dearomatization and Aromatization of Pincer Complexes Metal-Ligand Cooperation at Phosphine-Based Acceptor Pincer Ligands Metal-Ligand Cooperativity of Phosphorus-Containing Pincer Systems Cooperative Reactivity by Pincer-Type Complexes Possessing Secondary Coordination Sphere Redox-Active Pincer Ligands A Pincer Motif Etched into a meta-benziporphyrin frame The Role of Metal-Ligand Cooperation in Manganese(I)-Catalyzed Hydrogenation/Dehydrogenation Reactions Hydrogenation Reactions Catalyzed by PNP-Type Complexes Featuring a HN(CH2CH2PR2)2 ligand Catalytic Conversion of Nitriles by Metal Pincer Complexes The Application of Pincer Ligand in Catalytic Water Splitting Correction to: Metal-Ligand Cooperativity of Phosphorus-Containing Pincer Systems".
Cote :	EXCLU (SdL)
Num_Inv :	3611
Localisation :	LCC (SdL)

Topics in Organometallic Chemistry. Vol.68 : Metal-Ligand Co-operativity : Catalysis and the pincer-metal platform [texte imprimé] / Gerard van Koten, Éditeur scientifique ; Kirchner, Karl, Éditeur scientifique ; Moret, Marc-Etienne, Auteur . - Berlin, Heidelberg : Springer, 2021 . - x, 449 p.. - (Topics in Organometallic Chemistry, ISSN 1436-6002; 68) .
ISBN : 978-3-030-68915-5
The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal.
Langues : Anglais (eng)

Index. décimale :	EXCLU Ouvrages interdits de prêt
Résumé :	This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of significant recent developments in the area of metal-ligand cooperativity, with a focus on pincer architectures. The various contributions highlight the widespread impact of M–L co-operativity phenomena on modern organometallic chemistry and catalyst development. The development of efficient and selective catalytic transformations relies on the understanding and fine control of the various elementary reactions that constitutes a catalytic cycle. Co-operative ligands, which actively participate in bond making and bond breaking together to the metal they support, open up new avenues in this area. In particular, buttressing a weak or reactive metal-ligand bond by flanking coordinating arms in a pincer ligand design is proving a versatile strategy to access robust metal complexes that exhibit unusual and selective reactivity patterns.
Note de contenu :	"* Recent Advances in the Applications of Metal-Ligand Cooperation via Dearomatization and Aromatization of Pincer Complexes Metal-Ligand Cooperation at Phosphine-Based Acceptor Pincer Ligands Metal-Ligand Cooperativity of Phosphorus-Containing Pincer Systems Cooperative Reactivity by Pincer-Type Complexes Possessing Secondary Coordination Sphere Redox-Active Pincer Ligands A Pincer Motif Etched into a meta-benziporphyrin frame The Role of Metal-Ligand Cooperation in Manganese(I)-Catalyzed Hydrogenation/Dehydrogenation Reactions Hydrogenation Reactions Catalyzed by PNP-Type Complexes Featuring a HN(CH2CH2PR2)2 ligand Catalytic Conversion of Nitriles by Metal Pincer Complexes The Application of Pincer Ligand in Catalytic Water Splitting Correction to: Metal-Ligand Cooperativity of Phosphorus-Containing Pincer Systems".
Cote :	EXCLU (SdL)
Num_Inv :	3611
Localisation :	LCC (SdL)