The chemistry of platinum and palladium : with particular reference to complexes of the elements / Frank R. Hartley

Public ISBD Titre : The chemistry of platinum and palladium : with particular reference to complexes of the elements Type de document : texte imprimé Auteurs : Frank R. Hartley, Auteur Editeur : London : Applied Science Publishers Année de publication : 1973 Importance : xiii, 544 p. ISBN/ISSN/EAN : 978-0-85334-543-5 Note générale : COMPLEX COMPOUNDS Langues : Anglais (eng) Tags : COMPLEX COMPOUNDS Index. décimale : EQ -Equipe- Résumé : "The opening chapters contain a resume of the occurrence, extraction, properties and uses of platinum and palladium and a general survey of their oxidation states and the stereochemistries of their complexes. Descriptions of the preparations, structures and reactions of the compounds are divided according to the oxidation states of the metals. A single chapter suffices for the zero and +4 states, but there are six on the divalent state. The material for each state is classified according to the position in the periodic table of the donor atoms bound directly to the metal. There follows a discussion of the mechanism of the reactions, mainly relating to platinum complexes because their slower reaction rates make them easier to study. The reactions are considered from the point of view of the entering ligand, the leaving ligand, the substrate, the non-labile ligands with particular reference to their cis and trans effects, and the solvent. The organometallic chemistry is dealt with separately, as the oxidation state of the metal is of less importance than the nature of the ligand. The material is divided into three chapters on metal-carbon u-bonded compounds, olefin and acetylene compounds and finally z-allylic compounds. Complexes containing the cyanide, isocyanide, carbonyl and n-cyclopentadienyl ligands are considered at appropriate places in earlier chapters. As suggested in the subtitle, the emphasis has been placed on the complexes of the metals rather than on the traditional inorganic compounds. The treatment throughout is comparative, indicating the similarities and differences between the respective chemistries of platinum and palladium." Cote : LCC/L Num_Inv : 1455 The chemistry of platinum and palladium : with particular reference to complexes of the elements [texte imprimé] / Frank R. Hartley, Auteur . - London : Applied Science Publishers, 1973 . - xiii, 544 p. ISBN : 978-0-85334-543-5 COMPLEX COMPOUNDS Langues : Anglais (eng) Tags : COMPLEX COMPOUNDS Index. décimale : EQ -Equipe- Résumé : "The opening chapters contain a resume of the occurrence, extraction, properties and uses of platinum and palladium and a general survey of their oxidation states and the stereochemistries of their complexes. Descriptions of the preparations, structures and reactions of the compounds are divided according to the oxidation states of the metals. A single chapter suffices for the zero and +4 states, but there are six on the divalent state. The material for each state is classified according to the position in the periodic table of the donor atoms bound directly to the metal. There follows a discussion of the mechanism of the reactions, mainly relating to platinum complexes because their slower reaction rates make them easier to study. The reactions are considered from the point of view of the entering ligand, the leaving ligand, the substrate, the non-labile ligands with particular reference to their cis and trans effects, and the solvent. The organometallic chemistry is dealt with separately, as the oxidation state of the metal is of less importance than the nature of the ligand. The material is divided into three chapters on metal-carbon u-bonded compounds, olefin and acetylene compounds and finally z-allylic compounds. Complexes containing the cyanide, isocyanide, carbonyl and n-cyclopentadienyl ligands are considered at appropriate places in earlier chapters. As suggested in the subtitle, the emphasis has been placed on the complexes of the metals rather than on the traditional inorganic compounds. The treatment throughout is comparative, indicating the similarities and differences between the respective chemistries of platinum and palladium." Cote : LCC/L Num_Inv : 1455

Exemplaires(1)

Code-barres	Cote	Support	Localisation	Section	Disponibilité
1455	LCC/L	Texte imprimé	Equipe	Livre	Equipe - Demande préalable Disponible

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