Titre :	High- and low-valent tris-N-heterocyclic carbene iron complexes : a study of molecular and electronic structure
Type de document :	texte imprimé
Auteurs :	Carola S. Vogel
Editeur :	Berlin : Springer
Année de publication :	2012
Importance :	xviii, 132p.
Présentation :	98 illus., 66 illus. in color.
ISBN/ISSN/EAN :	978-3-642-27253-0
Langues :	Anglais (eng)
Catégories :	Chimie de coordination, Chimie organométallique, Métaux de transition
Tags :	CARBENE LIGANDS  HIGH VALENT IRON  IRON NITRIDES  MOSSBAUER SPECTROSCOPY  SPIN CROSSOVER
Index. décimale :	B-D
Résumé :	"Carola Vogel’s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. These studies show that quantitative yields of ammonia are given at ambient conditions. High valent iron nitride and oxo species have been proposed as key intermediates in many bio-catalytic transformations, but until now these species have proven exceedingly challenging to isolate and study. Iron complexes in high oxidation states can thus serve as models for iron-containing enzymes to help us understand biological systems or aid our development of more efficient industrial catalysts."
Cote :	B-D184 (SdS)
Num_Inv :	3143

High- and low-valent tris-N-heterocyclic carbene iron complexes : a study of molecular and electronic structure [texte imprimé] / Carola S. Vogel . - Berlin : Springer, 2012 . - xviii, 132p. : 98 illus., 66 illus. in color.
ISBN : 978-3-642-27253-0
Langues : Anglais (eng)

Catégories :	Chimie de coordination, Chimie organométallique, Métaux de transition
Tags :	CARBENE LIGANDS  HIGH VALENT IRON  IRON NITRIDES  MOSSBAUER SPECTROSCOPY  SPIN CROSSOVER
Index. décimale :	B-D
Résumé :	"Carola Vogel’s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. These studies show that quantitative yields of ammonia are given at ambient conditions. High valent iron nitride and oxo species have been proposed as key intermediates in many bio-catalytic transformations, but until now these species have proven exceedingly challenging to isolate and study. Iron complexes in high oxidation states can thus serve as models for iron-containing enzymes to help us understand biological systems or aid our development of more efficient industrial catalysts."
Cote :	B-D184 (SdS)
Num_Inv :	3143