Unusual structures and physical properties in organometallic chemistry / Marcel Gielen

Public ISBD Titre : Unusual structures and physical properties in organometallic chemistry Type de document : texte imprimé Auteurs : Marcel Gielen, Éditeur scientifique ; Rudolph Willem, Éditeur scientifique ; Bernd Wrackmeyer, Éditeur scientifique Editeur : West-Sussex Wiley Année de publication : 2008 Importance : xiii, 425 p. ISBN/ISSN/EAN : 978-0-471-49635-9 Langues : Anglais (eng) Catégories : Chimie de coordination, Chimie organométallique, Métaux de transition Tags : ORGANOMETALLIC CHEMISTRY  ORGANOMETALLICSPROPERTIES  CHEMISTRY-PHYSICAL  CHEMICAL STRUCTURE-PROPERTIES Index. décimale : B-D Résumé : The principal idea of this volume is to offer a Capita Selecta of unconventional and thought-provoking topics in organometallic chemistry, presented by experts in each field. As intended, this approach leads either to reviews covering a specific uncommon class of organometallic compounds or to overviews which relate uncommon physical properties with various classes of organometallic compounds. The contributions are streamlined thus onto two main axes - unusual properties reflecting structures and bonding situations, on the one hand, and uncommon structural features or structure-reactivity relationships, on the other. Extensive cross-referencing of useful information is provided, making this volume accessible for people working in rather different areas of organometallic chemistry. The synthesis of molecules with 'extreme' properties is a challenge for all those working in organometallic chemistry, irrelevant of theoretical/computational, synthetic or application interests. This book presents case studies at the interface of these overlapping interests. Unusual Structures and Physical Properties in Organometallic Chemistry: * Provides test cases for computational and theoretical models * Presents a challenge for synthetic chemists * Provides ideal show cases for analytical techniques This volume will be an invaluable reference for researchers in organometallic chemistry, computational and theoretical chemistry, NMR and other spectroscopic methods. Note de contenu : "* Structure and Electrochemistry of Transition Metal Carbonyl Clusters with Interstitial or Semi-Interstitial Atoms: Contrast between Nitrides or Phosphides and Carbides * Unusual Nuclear Magnetic Shielding and Coupling Constants Related to Unusual Bonding Situations * Deuterium Spin-Lattice Relaxation and Deuterium Quadrupole Coupling Constants. A Novel Strategy for Characterization of Transition Metal Hydrides and Dihydrogen Complexes in Solution * NMR Studies of Ligand Nuclei in Organometallic Compounds--New Information from Solid-State NMR Techniques * Metal Atom Motion in Some Iron Organometallics Magnetic Communication in Binuclear Organometallic Complexes Mediated by Carbon-Rich Bridges * Molecular Cluster Complexes with Facial Arene Ligands * Cobaltafulvenes and Cobaltapentalenes: Highly Polar Metallacyclic II-Systems with Unusual Properties * Novel Highly Nucleophilic Ylidic Ligands for the Preparation of Unusually Stable Metal Complexes * Supramolecular Interactions in Structures of Organic Antimony and Bismuth Compounds". Cote : B-D196 Num_Inv : 3500 Localisation : LCC (SdS) Unusual structures and physical properties in organometallic chemistry [texte imprimé] / Marcel Gielen, Éditeur scientifique ; Rudolph Willem, Éditeur scientifique ; Bernd Wrackmeyer, Éditeur scientifique . - West-Sussex Wiley, 2008 . - xiii, 425 p. ISBN : 978-0-471-49635-9 Langues : Anglais (eng) Catégories : Chimie de coordination, Chimie organométallique, Métaux de transition Tags : ORGANOMETALLIC CHEMISTRY  ORGANOMETALLICSPROPERTIES  CHEMISTRY-PHYSICAL  CHEMICAL STRUCTURE-PROPERTIES Index. décimale : B-D Résumé : The principal idea of this volume is to offer a Capita Selecta of unconventional and thought-provoking topics in organometallic chemistry, presented by experts in each field. As intended, this approach leads either to reviews covering a specific uncommon class of organometallic compounds or to overviews which relate uncommon physical properties with various classes of organometallic compounds. The contributions are streamlined thus onto two main axes - unusual properties reflecting structures and bonding situations, on the one hand, and uncommon structural features or structure-reactivity relationships, on the other. Extensive cross-referencing of useful information is provided, making this volume accessible for people working in rather different areas of organometallic chemistry. The synthesis of molecules with 'extreme' properties is a challenge for all those working in organometallic chemistry, irrelevant of theoretical/computational, synthetic or application interests. This book presents case studies at the interface of these overlapping interests. Unusual Structures and Physical Properties in Organometallic Chemistry: * Provides test cases for computational and theoretical models * Presents a challenge for synthetic chemists * Provides ideal show cases for analytical techniques This volume will be an invaluable reference for researchers in organometallic chemistry, computational and theoretical chemistry, NMR and other spectroscopic methods. Note de contenu : "* Structure and Electrochemistry of Transition Metal Carbonyl Clusters with Interstitial or Semi-Interstitial Atoms: Contrast between Nitrides or Phosphides and Carbides * Unusual Nuclear Magnetic Shielding and Coupling Constants Related to Unusual Bonding Situations * Deuterium Spin-Lattice Relaxation and Deuterium Quadrupole Coupling Constants. A Novel Strategy for Characterization of Transition Metal Hydrides and Dihydrogen Complexes in Solution * NMR Studies of Ligand Nuclei in Organometallic Compounds--New Information from Solid-State NMR Techniques * Metal Atom Motion in Some Iron Organometallics Magnetic Communication in Binuclear Organometallic Complexes Mediated by Carbon-Rich Bridges * Molecular Cluster Complexes with Facial Arene Ligands * Cobaltafulvenes and Cobaltapentalenes: Highly Polar Metallacyclic II-Systems with Unusual Properties * Novel Highly Nucleophilic Ylidic Ligands for the Preparation of Unusually Stable Metal Complexes * Supramolecular Interactions in Structures of Organic Antimony and Bismuth Compounds". Cote : B-D196 Num_Inv : 3500 Localisation : LCC (SdS)

Exemplaires(1)

Code-barres	Cote	Support	Localisation	Section	Disponibilité
3500	B-D196	Texte imprimé	Bibliothèque	Livre	Disponible

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