Titre :	The chemistry of free radical polymerization
Type de document :	texte imprimé
Auteurs :	Graeme Moad, Auteur ; David H. Solomon, Auteur
Editeur :	Oxford : Pergamon
Année de publication :	1995
Importance :	xv, 408 p.
ISBN/ISSN/EAN :	978-0-08-042078-3
Langues :	Anglais (eng)
Tags :	POLYMERIZATION  FREE RADICALS-Chemistry
Index. décimale :	EQ -Equipe-
Résumé :	"The overall aim of this work is to provide a framework for greater understanding of free radical polymerization. Each chapter describes some of the techniques that have been employed to characterize polymers and polymerizations."
Note de contenu :	"* Free radical reactions: introduction; addition to carbon-carbon double bonds; steric factors; polar factors; bond strengths; theoretical treatments; hydrogen atom transfer; polar factors; stereoelectronic factors; reaction conditions; abstraction vs. addition; summary radical-radical reactions; pathways for combination; pathways for disproportionation; combination vs. disproportionation; summary * Initiation: introduction; the initiation process; reaction with monomer; fragmentation; reaction with solvents, additives or impurities; effects of the reaction medium on radical reactivity; reaction with oxygen; initiator efficiency; cage reaction and initiator-derived by-products; primary radical termination; transfer to initiator; initiation in heterogeneous polymerization; thermal initiation; the radicals; carbon-centred radicals; oxygen-centred radicals * Propagation: introduction; stereosequence isomerism - tacticity; monoene polymers; conjugated diene polymers; structural isomerism - rearrangement; cyclopolymerization; ring-opening polymerization; intramolecular atom transfer; propagation kinetics and thermodynamics. * Termination; introduction; radical-radical termination; termination kinetics; disproportionation vs. combination - general considerations; disproportionation vs. combination - summary; chain transfer; mechanisms; transfer agents; transfer to monomer; transfer to polymer; inhibition and retardation; "stable" radicals; oxygen * Copolymerization: introduction; statistical copolymerization; copolymerization mechanisms; block and graft copolymerization; end-functional polymers; block and graft copolymer synthesis * Controlling polymerization: introduction; "defect structures" in polystyrene; "defect structures" in poly(methyl methacrylate); controlling propagation; solvent; Lewis acids and inorganics; template polymers; compositional heterogeneity in copolymers; agents for controlling termination; organosulfur iniferters; hexasubstituted ethanes and azo compounds; alkoxyamines and related species"
Cote :	LCC/P
Num_Inv :	1753

The chemistry of free radical polymerization [texte imprimé] / Graeme Moad, Auteur ; David H. Solomon, Auteur . - Oxford : Pergamon, 1995 . - xv, 408 p.
ISBN : 978-0-08-042078-3
Langues : Anglais (eng)

Tags :	POLYMERIZATION  FREE RADICALS-Chemistry
Index. décimale :	EQ -Equipe-
Résumé :	"The overall aim of this work is to provide a framework for greater understanding of free radical polymerization. Each chapter describes some of the techniques that have been employed to characterize polymers and polymerizations."
Note de contenu :	"* Free radical reactions: introduction; addition to carbon-carbon double bonds; steric factors; polar factors; bond strengths; theoretical treatments; hydrogen atom transfer; polar factors; stereoelectronic factors; reaction conditions; abstraction vs. addition; summary radical-radical reactions; pathways for combination; pathways for disproportionation; combination vs. disproportionation; summary * Initiation: introduction; the initiation process; reaction with monomer; fragmentation; reaction with solvents, additives or impurities; effects of the reaction medium on radical reactivity; reaction with oxygen; initiator efficiency; cage reaction and initiator-derived by-products; primary radical termination; transfer to initiator; initiation in heterogeneous polymerization; thermal initiation; the radicals; carbon-centred radicals; oxygen-centred radicals * Propagation: introduction; stereosequence isomerism - tacticity; monoene polymers; conjugated diene polymers; structural isomerism - rearrangement; cyclopolymerization; ring-opening polymerization; intramolecular atom transfer; propagation kinetics and thermodynamics. * Termination; introduction; radical-radical termination; termination kinetics; disproportionation vs. combination - general considerations; disproportionation vs. combination - summary; chain transfer; mechanisms; transfer agents; transfer to monomer; transfer to polymer; inhibition and retardation; "stable" radicals; oxygen * Copolymerization: introduction; statistical copolymerization; copolymerization mechanisms; block and graft copolymerization; end-functional polymers; block and graft copolymer synthesis * Controlling polymerization: introduction; "defect structures" in polystyrene; "defect structures" in poly(methyl methacrylate); controlling propagation; solvent; Lewis acids and inorganics; template polymers; compositional heterogeneity in copolymers; agents for controlling termination; organosulfur iniferters; hexasubstituted ethanes and azo compounds; alkoxyamines and related species"
Cote :	LCC/P
Num_Inv :	1753