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Titre : Chemical kinetics and dynamics : Couverture , , Type de document : texte imprimé Auteurs : Jeffrey I. Steinfeld ; Joseph S. Francisco ; William L. Hase Mention d'édition : Second edition Editeur : New-York : Prentice Hall Année de publication : 1999 Importance : 518 p. ISBN/ISSN/EAN : 978-0-13-737123-5 Langues : Anglais (eng) Tags : CHEMICAL KINETICS MOLECULAR DYNAMICS Index. décimale : EQ -Equipe- Résumé : "Presents a balanced presentation of the macroscopic view of empirical kinetics and the microscopic molecular viewpoint of chemical dynamics.Stressing interconnections between phenomenological chemical kinetics and molecular reaction dynamics, the book discusses reactions in gas phase, liquids, and at surfaces; molecular potential surfaces; gas-gas and gas-surface theories applied to reactive collisions. It features applications to atmospheric chemistry, combustion, and chemical lasers as well as multiple methods for solving kinetic equations. It also addresses topics not found in other books: Information theory, Stochastic simulation, and Sensitivity analysis. The second edition of Chemical Kinetics and Dynamics has been revised to include the latest information as well as new topics, such as heterogeneous reactions in atmospheric chemistry, reactant product imaging, and molecular dynamics of H + H2. It provides an experimental observation of the transition state ("Femtochemistry"); new treatment of stratospheric chemistry, including heterogeneous processes, balance among catalytic cycles, environmental consequences, and policy implications as well as current database information on NIST kinetics as well as JPL evaluations. A valuable resource on kinetics for professional atmospheric kineticists and chemical engineers." Cote : LCC/E Num_Inv : 2215 Chemical kinetics and dynamics : Couverture , , [texte imprimé] / Jeffrey I. Steinfeld ; Joseph S. Francisco ; William L. Hase . - Second edition . - New-York : Prentice Hall, 1999 . - 518 p.
ISBN : 978-0-13-737123-5
Langues : Anglais (eng)
Tags : CHEMICAL KINETICS MOLECULAR DYNAMICS Index. décimale : EQ -Equipe- Résumé : "Presents a balanced presentation of the macroscopic view of empirical kinetics and the microscopic molecular viewpoint of chemical dynamics.Stressing interconnections between phenomenological chemical kinetics and molecular reaction dynamics, the book discusses reactions in gas phase, liquids, and at surfaces; molecular potential surfaces; gas-gas and gas-surface theories applied to reactive collisions. It features applications to atmospheric chemistry, combustion, and chemical lasers as well as multiple methods for solving kinetic equations. It also addresses topics not found in other books: Information theory, Stochastic simulation, and Sensitivity analysis. The second edition of Chemical Kinetics and Dynamics has been revised to include the latest information as well as new topics, such as heterogeneous reactions in atmospheric chemistry, reactant product imaging, and molecular dynamics of H + H2. It provides an experimental observation of the transition state ("Femtochemistry"); new treatment of stratospheric chemistry, including heterogeneous processes, balance among catalytic cycles, environmental consequences, and policy implications as well as current database information on NIST kinetics as well as JPL evaluations. A valuable resource on kinetics for professional atmospheric kineticists and chemical engineers." Cote : LCC/E Num_Inv : 2215 Exemplaires(1)
Code-barres Cote Support Localisation Section Disponibilité 2215 LCC/E Texte imprimé Equipe Livre Equipe - Demande préalable
Disponible
Titre : Reactions of metallic salts and complexes and, organometallic compounds Type de document : texte imprimé Auteurs : Clement H. Bamford, Éditeur scientifique ; Charles F. H. Tipper, Éditeur scientifique Editeur : Amsterdam : Elsevier Année de publication : 1972 Collection : Comprehensive Chemical Kinetics num. 7 Importance : xv, 615 p. ISBN/ISSN/EAN : 978-0-08-086802-8 Langues : Anglais (eng) Catégories : Méthodes d'Analyses Tags : CHEMICAL KINETICS METAL COMPLEXES--Reactivity ORGANOMETALLIC COMPOUNDS--Reactivity CHEMICAL REACTIONS Index. décimale : B-B Note de contenu : "* Reactions of inert complexes and metal organic compounds
* Reactions in solution between various metal ions of the same element in different oxidation states
* Oxidation-reduction reactions between complexes of different metals
* Oxidation-reduction reactions between covalent compounds and metal ions
* Induced reactions."Cote : B-B047 Num_Inv : 00163 Localisation : LCC (SdS) Reactions of metallic salts and complexes and, organometallic compounds [texte imprimé] / Clement H. Bamford, Éditeur scientifique ; Charles F. H. Tipper, Éditeur scientifique . - Amsterdam : Elsevier, 1972 . - xv, 615 p.. - (Comprehensive Chemical Kinetics; 7) .
ISBN : 978-0-08-086802-8
Langues : Anglais (eng)
Catégories : Méthodes d'Analyses Tags : CHEMICAL KINETICS METAL COMPLEXES--Reactivity ORGANOMETALLIC COMPOUNDS--Reactivity CHEMICAL REACTIONS Index. décimale : B-B Note de contenu : "* Reactions of inert complexes and metal organic compounds
* Reactions in solution between various metal ions of the same element in different oxidation states
* Oxidation-reduction reactions between complexes of different metals
* Oxidation-reduction reactions between covalent compounds and metal ions
* Induced reactions."Cote : B-B047 Num_Inv : 00163 Localisation : LCC (SdS) Exemplaires(1)
Code-barres Cote Support Localisation Section Disponibilité 00163 B-B047 Texte imprimé Bibliothèque Livre Disponible
Titre : Investigation of rates and mechanisms of reactions. Part I Type de document : texte imprimé Auteurs : S. L. Friess, Éditeur scientifique ; Edward S. Lewis, Éditeur scientifique ; Arnold Weissberger, Éditeur scientifique Mention d'édition : 2nd revised Editeur : New-York : Interscience Publishers Année de publication : 1961 Collection : Technique of organic chemistry, ISSN 0082-240X num. 8-1 Importance : xii, 702 p. Langues : Anglais (eng) Catégories : Chimie organique Tags : CHEMICAL KINETICS PHYSICAL ORGANIC CHEMISTRY CHEMICAL REACTION-Conditions and laws Résumé : "These volumes contain reviews of methods which are applied to the determination of reaction rates and mechanisms. This is a "Second Completely Revised and Augmented Edition." This new edition contains 27 chapters, each of which considers some aspect of the subject. Since there is a different author for each chapter, the writing style and the type of material included varies greatly. For example, one author will carefully state the limits of applicability of s derivation and the next may give a dogmatic statement,. An author whose chapter appears later in the book may not refer back on. previous chapter. For example, the discussion of the transition state theory occurs at least twice. The discussions of the acidity function are mother instance of lark of careful editorial work. On page 522, "The success of the diagnostic use of the acidity function.. . has been striking," and on 1463, "The conflicting evidence and doubts … somewhat diminish its value as a diagnostic criterion." The last two quotes certainly indicate a difference of opinion between "experts" in the field. The unwary reader who has had little experience with acidity functions could be misled by rending the first, optimistic statement with no reference to the second. One additional objection is that the second edition repeats four or five chapter from the first edition. These are essentially unchanged, and add considerably to the cost of the book. The contents of these volumes are too diverse to comment upon in detail. The expansion has been largely in the field of Rapid and Very Rapid Reactions. Chapters 15 to 20 include a discussion of Relaxation Methods, Flash Photolysis, Magnetic Resonance Methods, Electrochemical Methods and Photostationary Methods. The study of non-kinetic methods has been somewhat less fully expanded in the discussions of thermodynamics, product criterion of mechanism, evidence for the formation of intermediates in organic reactions, use of isotopes, and tagged groups, stereochemistry and mechanism. These chapters contain many examples of mechanistic criteria that may be used; as well as 8, discussion of their limits. Krevoy's conclusion, "None of the methods of determining mechanism outlined in this chapter is completely reliable," and Saunders' topic, Pitfalls of Tracer Work, illustrate the care used by these authors to evaluate these techniques. The chapter on the interpretation of rate data. is also new. This discussion covers practical aspects of determining rate constants and the data that may be derived from these. The second part includes the general questions of linear free energy relationships, e.g., the Hammett equation, the Taft equation, etc. The Iast part presents an analysis of classic experiments in which the "new factor," the effect of structure on reactivity, was discovered. This carefully written chapter is well worth the consideration of the practicing organic chemist. To summarize, these volumes contain much valuable information for the organic chemist. The convenient summary of data and idem by the experts in the field outweighs the editorially uneven quality of the final product." Cote : B-C051 (SdS) Num_Inv : 233 Investigation of rates and mechanisms of reactions. Part I [texte imprimé] / S. L. Friess, Éditeur scientifique ; Edward S. Lewis, Éditeur scientifique ; Arnold Weissberger, Éditeur scientifique . - 2nd revised . - New-York : Interscience Publishers, 1961 . - xii, 702 p.. - (Technique of organic chemistry, ISSN 0082-240X; 8-1) .
Langues : Anglais (eng)
Catégories : Chimie organique Tags : CHEMICAL KINETICS PHYSICAL ORGANIC CHEMISTRY CHEMICAL REACTION-Conditions and laws Résumé : "These volumes contain reviews of methods which are applied to the determination of reaction rates and mechanisms. This is a "Second Completely Revised and Augmented Edition." This new edition contains 27 chapters, each of which considers some aspect of the subject. Since there is a different author for each chapter, the writing style and the type of material included varies greatly. For example, one author will carefully state the limits of applicability of s derivation and the next may give a dogmatic statement,. An author whose chapter appears later in the book may not refer back on. previous chapter. For example, the discussion of the transition state theory occurs at least twice. The discussions of the acidity function are mother instance of lark of careful editorial work. On page 522, "The success of the diagnostic use of the acidity function.. . has been striking," and on 1463, "The conflicting evidence and doubts … somewhat diminish its value as a diagnostic criterion." The last two quotes certainly indicate a difference of opinion between "experts" in the field. The unwary reader who has had little experience with acidity functions could be misled by rending the first, optimistic statement with no reference to the second. One additional objection is that the second edition repeats four or five chapter from the first edition. These are essentially unchanged, and add considerably to the cost of the book. The contents of these volumes are too diverse to comment upon in detail. The expansion has been largely in the field of Rapid and Very Rapid Reactions. Chapters 15 to 20 include a discussion of Relaxation Methods, Flash Photolysis, Magnetic Resonance Methods, Electrochemical Methods and Photostationary Methods. The study of non-kinetic methods has been somewhat less fully expanded in the discussions of thermodynamics, product criterion of mechanism, evidence for the formation of intermediates in organic reactions, use of isotopes, and tagged groups, stereochemistry and mechanism. These chapters contain many examples of mechanistic criteria that may be used; as well as 8, discussion of their limits. Krevoy's conclusion, "None of the methods of determining mechanism outlined in this chapter is completely reliable," and Saunders' topic, Pitfalls of Tracer Work, illustrate the care used by these authors to evaluate these techniques. The chapter on the interpretation of rate data. is also new. This discussion covers practical aspects of determining rate constants and the data that may be derived from these. The second part includes the general questions of linear free energy relationships, e.g., the Hammett equation, the Taft equation, etc. The Iast part presents an analysis of classic experiments in which the "new factor," the effect of structure on reactivity, was discovered. This carefully written chapter is well worth the consideration of the practicing organic chemist. To summarize, these volumes contain much valuable information for the organic chemist. The convenient summary of data and idem by the experts in the field outweighs the editorially uneven quality of the final product." Cote : B-C051 (SdS) Num_Inv : 233 Exemplaires(1)
Code-barres Cote Support Localisation Section Disponibilité 233 B-C051 Texte imprimé Bibliothèque Livre Disponible
Titre : Investigation of rates and mechanisms of reactions : Part I: General considerations and reactions at conventional rates Type de document : texte imprimé Auteurs : Edward S. Lewis, Éditeur scientifique Mention d'édition : Third edition Editeur : New York : John Wiley & Sons Année de publication : 1974 Collection : Techniques of Chemistry num. VI Importance : 2 vol., 1: xiii, 838 p. ISBN/ISSN/EAN : 978-0-471-93095-2 Langues : Anglais (eng) Catégories : Chimie organique Tags : CHEMICAL KINETICS CHEMICAL REACTIONS Index. décimale : B-C Note de contenu : "Part I:
* General methods of rate and mechanism study
* Activated-complex theory: current status, extensions, and applications
* Homogeneous gas-phase reactions
* Kinetics in solution
* Kinetic isotope effects
* Tracer methods
* Stereochemistry and reaction mechanism
* From kinetic data to reaction mechanism
* Kinetics of complex reactions
* Homogeneous inorganic reactions
* Homogeneous-solution catalysis by small molecules and by enzimes
* Mechanism in heterogeneous catalysis
* Use of computers
* Linear-free energy relations."
Cote : B-C049 (SdS) Num_Inv : 231 Investigation of rates and mechanisms of reactions : Part I: General considerations and reactions at conventional rates [texte imprimé] / Edward S. Lewis, Éditeur scientifique . - Third edition . - New York : John Wiley & Sons, 1974 . - 2 vol., 1: xiii, 838 p.. - (Techniques of Chemistry; VI) .
ISBN : 978-0-471-93095-2
Langues : Anglais (eng)
Catégories : Chimie organique Tags : CHEMICAL KINETICS CHEMICAL REACTIONS Index. décimale : B-C Note de contenu : "Part I:
* General methods of rate and mechanism study
* Activated-complex theory: current status, extensions, and applications
* Homogeneous gas-phase reactions
* Kinetics in solution
* Kinetic isotope effects
* Tracer methods
* Stereochemistry and reaction mechanism
* From kinetic data to reaction mechanism
* Kinetics of complex reactions
* Homogeneous inorganic reactions
* Homogeneous-solution catalysis by small molecules and by enzimes
* Mechanism in heterogeneous catalysis
* Use of computers
* Linear-free energy relations."
Cote : B-C049 (SdS) Num_Inv : 231 Exemplaires(1)
Code-barres Cote Support Localisation Section Disponibilité 231 B-C049 Texte imprimé Bibliothèque Livre Disponible
Titre : Investigation of rates and mechanisms of reactions : Part II: Investigation of elementary reaction steps in solution and very fast reactions Type de document : texte imprimé Auteurs : Gordon G. Hammes, Éditeur scientifique Mention d'édition : Third edition Editeur : New York : John Wiley & Sons Année de publication : 1974 Collection : Techniques of Chemistry num. VI Importance : 2 vol., 2: xiii, 665 p. ISBN/ISSN/EAN : 978-0-471-93127-0 Langues : Anglais (eng) Catégories : Chimie organique Tags : CHEMICAL KINETICS CHEMICAL REACTIONS Index. décimale : B-C Note de contenu : "Part II:
* Introduction
* Rapid flow methods
* Theoretical basis of relaxation spectrometry
* Temperature-jump methods
* Pressure-jump methods
* Electric field methods
* Ultrasonic methods
* Electrochemical methods for the investigation of fast chemical reactions
* Photostationary methods
* Flash photolysis
* Pulse radiolysis
* Nuclear magnetic resonance
* Electron paramagnetic resonance."Cote : B-C050 (SdS) Num_Inv : 232 Investigation of rates and mechanisms of reactions : Part II: Investigation of elementary reaction steps in solution and very fast reactions [texte imprimé] / Gordon G. Hammes, Éditeur scientifique . - Third edition . - New York : John Wiley & Sons, 1974 . - 2 vol., 2: xiii, 665 p.. - (Techniques of Chemistry; VI) .
ISBN : 978-0-471-93127-0
Langues : Anglais (eng)
Catégories : Chimie organique Tags : CHEMICAL KINETICS CHEMICAL REACTIONS Index. décimale : B-C Note de contenu : "Part II:
* Introduction
* Rapid flow methods
* Theoretical basis of relaxation spectrometry
* Temperature-jump methods
* Pressure-jump methods
* Electric field methods
* Ultrasonic methods
* Electrochemical methods for the investigation of fast chemical reactions
* Photostationary methods
* Flash photolysis
* Pulse radiolysis
* Nuclear magnetic resonance
* Electron paramagnetic resonance."Cote : B-C050 (SdS) Num_Inv : 232 Exemplaires(1)
Code-barres Cote Support Localisation Section Disponibilité 232 B-C050 Texte imprimé Bibliothèque Livre Disponible PermalinkPermalinkPermalinkMetal-surface reaction energetics: Theory and applications to heterogeneous catalysis, chemisorption, and surface diffusion / Evgeny Shustorovich
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