6 recherche sur le tag 'physical organic chemistry'   

Dipole moments in organic chemistry / Vladimir I. Minkin

Public ISBD Titre : Dipole moments in organic chemistry Type de document : texte imprimé Auteurs : Vladimir I. Minkin ; Osip A. Osipov ; Yurii A. Zhdanov Editeur : New-York : Plenum Press Année de publication : 1970 Importance : xi, 288 p. ISBN/ISSN/EAN : 978-0-306-30408-8 Langues : Anglais (eng) Catégories : Chimie : Généralités Tags : PHYSICAL ORGANIC CHEMISTRY  DIPOLE MOMENTS Index. décimale : B-A Note de contenu : "* Basic principles of the theory of dielectrics * Nature of the dipole moment and methods for its determination * Calculations in the dipole moment method * Dipole moments and the stereochemistry of organic compounds * Dipole moments and the electronic structure of organic compounds * Dipole moments and some special problems of the structure and properties of organic compounds." Cote : B-A075 (SdS) Num_Inv : 75 Dipole moments in organic chemistry [texte imprimé] / Vladimir I. Minkin ; Osip A. Osipov ; Yurii A. Zhdanov . - New-York : Plenum Press, 1970 . - xi, 288 p. ISBN : 978-0-306-30408-8 Langues : Anglais (eng) Catégories : Chimie : Généralités Tags : PHYSICAL ORGANIC CHEMISTRY  DIPOLE MOMENTS Index. décimale : B-A Note de contenu : "* Basic principles of the theory of dielectrics * Nature of the dipole moment and methods for its determination * Calculations in the dipole moment method * Dipole moments and the stereochemistry of organic compounds * Dipole moments and the electronic structure of organic compounds * Dipole moments and some special problems of the structure and properties of organic compounds." Cote : B-A075 (SdS) Num_Inv : 75

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75	B-A075	Texte imprimé	Bibliothèque	Livre	Disponible

Molecular orbitals and organic chemical reactions. Reference edition / Ian Fleming

Public ISBD Titre : Molecular orbitals and organic chemical reactions. Reference edition Type de document : texte imprimé Auteurs : Ian Fleming Editeur : Oxford : Wiley Année de publication : 2010 Importance : xii, 515 p. Présentation : ill. Format : 26 cm ISBN/ISSN/EAN : 978-0-470-74658-5 Langues : Anglais (eng) Catégories : Chimie organique Tags : MOLECULAR ORBITALS  CHEMICAL BONDS  PHYSICAL ORGANIC CHEMISTRY Index. décimale : B-C Résumé : "This expanded Reference Edition of Molecular Orbitals and Organic Chemical Reactions takes the content and the same non-mathematical approach of the Student Edition, and adds extensive extra subject coverage, detail and over 1500 references. The additional material adds a deeper understanding of the models used, and includes a broader range of applications and case studies. Providing a complete in-depth reference for a more advanced audience, this edition will find a place on the bookshelves of researchers and advanced students of organic, physical organic and computational chemistry." Cote : B-C088 (SdS) Num_Inv : 3003 Molecular orbitals and organic chemical reactions. Reference edition [texte imprimé] / Ian Fleming . - Oxford : Wiley, 2010 . - xii, 515 p. : ill. ; 26 cm. ISBN : 978-0-470-74658-5 Langues : Anglais (eng) Catégories : Chimie organique Tags : MOLECULAR ORBITALS  CHEMICAL BONDS  PHYSICAL ORGANIC CHEMISTRY Index. décimale : B-C Résumé : "This expanded Reference Edition of Molecular Orbitals and Organic Chemical Reactions takes the content and the same non-mathematical approach of the Student Edition, and adds extensive extra subject coverage, detail and over 1500 references. The additional material adds a deeper understanding of the models used, and includes a broader range of applications and case studies. Providing a complete in-depth reference for a more advanced audience, this edition will find a place on the bookshelves of researchers and advanced students of organic, physical organic and computational chemistry." Cote : B-C088 (SdS) Num_Inv : 3003

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3003	B-C088	Texte imprimé	Bibliothèque	Livre	Disponible

Ozone and its reactions with organic compounds / S. D. Razumovskii

Public ISBD Titre : Ozone and its reactions with organic compounds Type de document : texte imprimé Auteurs : S. D. Razumovskii, Auteur ; Gennadi Efremovitch Zaikof, Auteur Editeur : Amsterdam : Elsevier Année de publication : 1984 Collection : Studies in organic chemistry num. 15 Importance : x, 403 p. ISBN/ISSN/EAN : 978-0-444-42369-6 Langues : Anglais (eng) Langues originales : Russe (rus) Tags : ORGANIC COMPOUNDS  ORGANIC CHEMISTRY  PHYSICAL ORGANIC CHEMISTRY Index. décimale : EQ -Equipe- Cote : LCC/K Num_Inv : 527 Ozone and its reactions with organic compounds [texte imprimé] / S. D. Razumovskii, Auteur ; Gennadi Efremovitch Zaikof, Auteur . - Amsterdam : Elsevier, 1984 . - x, 403 p.. - (Studies in organic chemistry; 15) . ISBN : 978-0-444-42369-6 Langues : Anglais (eng) Langues originales : Russe (rus) Tags : ORGANIC COMPOUNDS  ORGANIC CHEMISTRY  PHYSICAL ORGANIC CHEMISTRY Index. décimale : EQ -Equipe- Cote : LCC/K Num_Inv : 527

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527	LCC/K	Texte imprimé	Equipe	Livre	Equipe - Demande préalable Disponible

Investigation of rates and mechanisms of reactions. Part I / S. L. Friess

Public ISBD Titre : Investigation of rates and mechanisms of reactions. Part I Type de document : texte imprimé Auteurs : S. L. Friess, Éditeur scientifique ; Edward S. Lewis, Éditeur scientifique ; Arnold Weissberger, Éditeur scientifique Mention d'édition : 2nd revised Editeur : New-York : Interscience Publishers Année de publication : 1961 Collection : Technique of organic chemistry, ISSN 0082-240X num. 8-1 Importance : xii, 702 p. Langues : Anglais (eng) Catégories : Chimie organique Tags : CHEMICAL KINETICS  PHYSICAL ORGANIC CHEMISTRY  CHEMICAL REACTION-Conditions and laws Résumé : "These volumes contain reviews of methods which are applied to the determination of reaction rates and mechanisms. This is a "Second Completely Revised and Augmented Edition." This new edition contains 27 chapters, each of which considers some aspect of the subject. Since there is a different author for each chapter, the writing style and the type of material included varies greatly. For example, one author will carefully state the limits of applicability of s derivation and the next may give a dogmatic statement,. An author whose chapter appears later in the book may not refer back on. previous chapter. For example, the discussion of the transition state theory occurs at least twice. The discussions of the acidity function are mother instance of lark of careful editorial work. On page 522, "The success of the diagnostic use of the acidity function.. . has been striking," and on 1463, "The conflicting evidence and doubts … somewhat diminish its value as a diagnostic criterion." The last two quotes certainly indicate a difference of opinion between "experts" in the field. The unwary reader who has had little experience with acidity functions could be misled by rending the first, optimistic statement with no reference to the second. One additional objection is that the second edition repeats four or five chapter from the first edition. These are essentially unchanged, and add considerably to the cost of the book. The contents of these volumes are too diverse to comment upon in detail. The expansion has been largely in the field of Rapid and Very Rapid Reactions. Chapters 15 to 20 include a discussion of Relaxation Methods, Flash Photolysis, Magnetic Resonance Methods, Electrochemical Methods and Photostationary Methods. The study of non-kinetic methods has been somewhat less fully expanded in the discussions of thermodynamics, product criterion of mechanism, evidence for the formation of intermediates in organic reactions, use of isotopes, and tagged groups, stereochemistry and mechanism. These chapters contain many examples of mechanistic criteria that may be used; as well as 8, discussion of their limits. Krevoy's conclusion, "None of the methods of determining mechanism outlined in this chapter is completely reliable," and Saunders' topic, Pitfalls of Tracer Work, illustrate the care used by these authors to evaluate these techniques. The chapter on the interpretation of rate data. is also new. This discussion covers practical aspects of determining rate constants and the data that may be derived from these. The second part includes the general questions of linear free energy relationships, e.g., the Hammett equation, the Taft equation, etc. The Iast part presents an analysis of classic experiments in which the "new factor," the effect of structure on reactivity, was discovered. This carefully written chapter is well worth the consideration of the practicing organic chemist. To summarize, these volumes contain much valuable information for the organic chemist. The convenient summary of data and idem by the experts in the field outweighs the editorially uneven quality of the final product." Cote : B-C051 (SdS) Num_Inv : 233 Investigation of rates and mechanisms of reactions. Part I [texte imprimé] / S. L. Friess, Éditeur scientifique ; Edward S. Lewis, Éditeur scientifique ; Arnold Weissberger, Éditeur scientifique  . -  2nd revised . - New-York : Interscience Publishers, 1961 . - xii, 702 p.. - (Technique of organic chemistry, ISSN 0082-240X; 8-1) . Langues : Anglais (eng) Catégories : Chimie organique Tags : CHEMICAL KINETICS  PHYSICAL ORGANIC CHEMISTRY  CHEMICAL REACTION-Conditions and laws Résumé : "These volumes contain reviews of methods which are applied to the determination of reaction rates and mechanisms. This is a "Second Completely Revised and Augmented Edition." This new edition contains 27 chapters, each of which considers some aspect of the subject. Since there is a different author for each chapter, the writing style and the type of material included varies greatly. For example, one author will carefully state the limits of applicability of s derivation and the next may give a dogmatic statement,. An author whose chapter appears later in the book may not refer back on. previous chapter. For example, the discussion of the transition state theory occurs at least twice. The discussions of the acidity function are mother instance of lark of careful editorial work. On page 522, "The success of the diagnostic use of the acidity function.. . has been striking," and on 1463, "The conflicting evidence and doubts … somewhat diminish its value as a diagnostic criterion." The last two quotes certainly indicate a difference of opinion between "experts" in the field. The unwary reader who has had little experience with acidity functions could be misled by rending the first, optimistic statement with no reference to the second. One additional objection is that the second edition repeats four or five chapter from the first edition. These are essentially unchanged, and add considerably to the cost of the book. The contents of these volumes are too diverse to comment upon in detail. The expansion has been largely in the field of Rapid and Very Rapid Reactions. Chapters 15 to 20 include a discussion of Relaxation Methods, Flash Photolysis, Magnetic Resonance Methods, Electrochemical Methods and Photostationary Methods. The study of non-kinetic methods has been somewhat less fully expanded in the discussions of thermodynamics, product criterion of mechanism, evidence for the formation of intermediates in organic reactions, use of isotopes, and tagged groups, stereochemistry and mechanism. These chapters contain many examples of mechanistic criteria that may be used; as well as 8, discussion of their limits. Krevoy's conclusion, "None of the methods of determining mechanism outlined in this chapter is completely reliable," and Saunders' topic, Pitfalls of Tracer Work, illustrate the care used by these authors to evaluate these techniques. The chapter on the interpretation of rate data. is also new. This discussion covers practical aspects of determining rate constants and the data that may be derived from these. The second part includes the general questions of linear free energy relationships, e.g., the Hammett equation, the Taft equation, etc. The Iast part presents an analysis of classic experiments in which the "new factor," the effect of structure on reactivity, was discovered. This carefully written chapter is well worth the consideration of the practicing organic chemist. To summarize, these volumes contain much valuable information for the organic chemist. The convenient summary of data and idem by the experts in the field outweighs the editorially uneven quality of the final product." Cote : B-C051 (SdS) Num_Inv : 233

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233	B-C051	Texte imprimé	Bibliothèque	Livre	Disponible

Aspects of homogeneous catalysis / Renato Ugo

Public ISBD Titre : Aspects of homogeneous catalysis Type de document : texte imprimé Auteurs : Renato Ugo, Éditeur scientifique Editeur : Dordrecht : D. Reidel Publishing Company Année de publication : 1981 Collection : A series of advances num. 4 Importance : 204 p. ISBN/ISSN/EAN : 978-94-009-8371-7 Langues : Anglais (eng) Catégories : Catalyse Tags : PHYSICAL ORGANIC CHEMISTRY  HOMOGENEOUS CATALYSIS Note de contenu : "Metal-catalysed epoxidations of olefins with hydroperoxides; Introduction; Metal-catalysed epoxidations with hydrogen peroxide; Covalent metal peroxides as epoxidizing agents; Metal-catalysed epoxidations with alkyl hydroperoxides; Oxidation of other functional groups; Summary; Glossary of non-standard abbreviations; References * Homogeneous catalytic reduction of carbonyl, azomethine-, and nitro-groups; Introduction; Reduction of the carbonyl group; Reduction of schiff bases; Reduction of nitro-compounds; Dihydrogen evolution; Reaction mechanisms; Conclusions; Abbreviations for ligand names* References catalysis of diolefin reactions by n3-allyl metal complexes; Introduction.; Allyl-MT complexes: bonding and dynamic behavior; Oligomerisation, co-oligomerisation and polymerisation of diolefins; Relation between catalyst structure and kinetic and thermodynamic controls of butadiene oligo- and polymerisation processes; Isomerisation of diolefins; Heteroactivation of diolefins; Conclusions; References * Substrates and phosphorus ligands used in asymmetric homogeneous hydrogenations catalysed by rhodium complexes; Introduction;Table I: chiral phosphines used as ligands in the rhodium-catalysed asymmetric hydrogenation * Table 2: substrates in the rhodium-catalysed asymmetric hydrogenation References." Cote : B-E009 (SdS) Num_Inv : 360 Aspects of homogeneous catalysis [texte imprimé] / Renato Ugo, Éditeur scientifique . - Dordrecht : D. Reidel Publishing Company, 1981 . - 204 p.. - (A series of advances; 4) . ISBN : 978-94-009-8371-7 Langues : Anglais (eng) Catégories : Catalyse Tags : PHYSICAL ORGANIC CHEMISTRY  HOMOGENEOUS CATALYSIS Note de contenu : "Metal-catalysed epoxidations of olefins with hydroperoxides; Introduction; Metal-catalysed epoxidations with hydrogen peroxide; Covalent metal peroxides as epoxidizing agents; Metal-catalysed epoxidations with alkyl hydroperoxides; Oxidation of other functional groups; Summary; Glossary of non-standard abbreviations; References * Homogeneous catalytic reduction of carbonyl, azomethine-, and nitro-groups; Introduction; Reduction of the carbonyl group; Reduction of schiff bases; Reduction of nitro-compounds; Dihydrogen evolution; Reaction mechanisms; Conclusions; Abbreviations for ligand names* References catalysis of diolefin reactions by n3-allyl metal complexes; Introduction.; Allyl-MT complexes: bonding and dynamic behavior; Oligomerisation, co-oligomerisation and polymerisation of diolefins; Relation between catalyst structure and kinetic and thermodynamic controls of butadiene oligo- and polymerisation processes; Isomerisation of diolefins; Heteroactivation of diolefins; Conclusions; References * Substrates and phosphorus ligands used in asymmetric homogeneous hydrogenations catalysed by rhodium complexes; Introduction;Table I: chiral phosphines used as ligands in the rhodium-catalysed asymmetric hydrogenation * Table 2: substrates in the rhodium-catalysed asymmetric hydrogenation References." Cote : B-E009 (SdS) Num_Inv : 360

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360	B-E009	Texte imprimé	Bibliothèque	Livre	Disponible

NMR band handbook / Herman A. Szymanksi

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