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| Titre : |
Oxidation numbers and oxidation states |
| Type de document : |
texte imprimé |
| Auteurs : |
Christian K. Jorgensen |
| Editeur : |
Berlin, Heidelberg : Springer Verlag |
| Année de publication : |
1969 |
| Importance : |
291 p. |
| ISBN/ISSN/EAN : |
978-3-642-87760-5 |
| Langues : |
Anglais (eng) |
| Catégories : |
Généralités en Chimie
|
| Tags : |
THEORETICAL CHEMISTRY VALENCE |
| Index. décimale : |
B-A |
| Résumé : |
"The correlation of spectroscopic and chemical investigations in recent years has been highly beneficial of many reasons. Around 1950, no valid explanation was available of the colours of compounds of the five transition groups. Later, it was possible to identify the excited levels with those expected for an electron configuration with a definite number of electrons in the partly filled shell. It is not generally recognized that this is equivalent to determining spectroscopic oxidation states related to the preponderant electron configuration and not to estimates of the fractional atomic charges. This brings in an entirely different type of description than the formal oxidation numbers used for characterizing compounds and reaction schemes. However, it must be realized that collectively oxidized ligands, formation of cluster-complexes and catenation may prevent the oxidation state from being well-defined." |
| Cote : |
B-A053 |
| Num_Inv : |
00055 |
| Localisation : |
LCC (SdS) |
Oxidation numbers and oxidation states [texte imprimé] / Christian K. Jorgensen . - Berlin, Heidelberg : Springer Verlag, 1969 . - 291 p. ISBN : 978-3-642-87760-5 Langues : Anglais ( eng)
| Catégories : |
Généralités en Chimie
|
| Tags : |
THEORETICAL CHEMISTRY VALENCE |
| Index. décimale : |
B-A |
| Résumé : |
"The correlation of spectroscopic and chemical investigations in recent years has been highly beneficial of many reasons. Around 1950, no valid explanation was available of the colours of compounds of the five transition groups. Later, it was possible to identify the excited levels with those expected for an electron configuration with a definite number of electrons in the partly filled shell. It is not generally recognized that this is equivalent to determining spectroscopic oxidation states related to the preponderant electron configuration and not to estimates of the fractional atomic charges. This brings in an entirely different type of description than the formal oxidation numbers used for characterizing compounds and reaction schemes. However, it must be realized that collectively oxidized ligands, formation of cluster-complexes and catenation may prevent the oxidation state from being well-defined." |
| Cote : |
B-A053 |
| Num_Inv : |
00055 |
| Localisation : |
LCC (SdS) |
|  |
Exemplaires(2)
|
00055
|
B-A053 |
Texte imprimé |
Bibliothèque |
Livre
|
Disponible |
|
00056
|
B-A053 |
Texte imprimé |
Bibliothèque |
Livre
|
Disponible |

| Titre : |
Valence theory |
| Type de document : |
texte imprimé |
| Auteurs : |
John N. Murrell ; S.F.A. Kettle ; J.M. Tedder |
| Editeur : |
New York : John Wiley & Sons |
| Année de publication : |
1965 |
| Importance : |
401 p. |
| Langues : |
Anglais (eng) |
| Catégories : |
Chimie théorique
|
| Tags : |
CHEMISTRY-Physical and Theoretical VALENCE |
| Index. décimale : |
B-H |
| Résumé : |
"The book has been based on lectures given for the past four years at the University of Sheffield. Our experience has been that the student only obtains a full grasp of the subject when he has successfully tackled some problems, and we consider that the problems in this book are an essential part of the text; some of the problems provide proofs of statements made in the text. A student benefits most if he is given the minimum of help necessary to enable him to solve the problem. To take a step in this direction we have provided hints to the problems at the end of the book. The student should first try the problems without the hints, but with their help most students should be able to obtain the solutions.
The first five chapters are intended for first year students, since we feel that an early grasp of such concepts as the orbital and the electron-pair bond are necessary for any course in experimental chemistry. The more formal mathematical aspects of the book start in chapter 6 when it has been assumed that the student has received some mathematical training during his first year. These later chapters also assume a knowledge of other branches of chemistry." Authors' preface |
| Cote : |
B-H042 (SdS) |
| Num_Inv : |
419 |
Valence theory [texte imprimé] / John N. Murrell ; S.F.A. Kettle ; J.M. Tedder . - New York : John Wiley & Sons, 1965 . - 401 p. Langues : Anglais ( eng)
| Catégories : |
Chimie théorique
|
| Tags : |
CHEMISTRY-Physical and Theoretical VALENCE |
| Index. décimale : |
B-H |
| Résumé : |
"The book has been based on lectures given for the past four years at the University of Sheffield. Our experience has been that the student only obtains a full grasp of the subject when he has successfully tackled some problems, and we consider that the problems in this book are an essential part of the text; some of the problems provide proofs of statements made in the text. A student benefits most if he is given the minimum of help necessary to enable him to solve the problem. To take a step in this direction we have provided hints to the problems at the end of the book. The student should first try the problems without the hints, but with their help most students should be able to obtain the solutions.
The first five chapters are intended for first year students, since we feel that an early grasp of such concepts as the orbital and the electron-pair bond are necessary for any course in experimental chemistry. The more formal mathematical aspects of the book start in chapter 6 when it has been assumed that the student has received some mathematical training during his first year. These later chapters also assume a knowledge of other branches of chemistry." Authors' preface |
| Cote : |
B-H042 (SdS) |
| Num_Inv : |
419 |
|  |
Exemplaires(1)
|
419
|
B-H042 |
Texte imprimé |
Bibliothèque |
Livre
|
Disponible |

| Titre : |
Valence theory |
| Type de document : |
texte imprimé |
| Auteurs : |
John N. Murrell ; S.F.A. Kettle ; J.M. Tedder |
| Editeur : |
New York : John Wiley & Sons |
| Année de publication : |
1965 |
| Importance : |
xiii, 401 p. |
| Langues : |
Anglais (eng) |
| Tags : |
VALENCE |
| Index. décimale : |
B-S Ancien fonds |
| Résumé : |
"The book has been based on lectures given for the past four years at the University of Sheffield. Our experience has been that the student only obtains a full grasp of the subject when he has successfully tackled some problems, and we consider that the problems in this book are an essential part of the text; some of the problems provide proofs of statements made in the text. A student benefits most if he is given the minimum of help necessary to enable him to solve the problem. To take a step in this direction we have provided hints to the problems at the end of the book. The student should first try the problems without the hints, but with their help most students should be able to obtain the solutions.
The first five chapters are intended for first year students, since we feel that an early grasp of such concepts as the orbital and the electron-pair bond are necessary for any course in experimental chemistry. The more formal mathematical aspects of the book start in chapter 6 when it has been assumed that the student has received some mathematical training during his first year. These later chapters also assume a knowledge of other branches of chemistry." Authors' preface |
| Cote : |
B-S064 |
| Num_Inv : |
690 |
| Localisation : |
LCC (SdS) |
Valence theory [texte imprimé] / John N. Murrell ; S.F.A. Kettle ; J.M. Tedder . - New York : John Wiley & Sons, 1965 . - xiii, 401 p. Langues : Anglais ( eng)
| Tags : |
VALENCE |
| Index. décimale : |
B-S Ancien fonds |
| Résumé : |
"The book has been based on lectures given for the past four years at the University of Sheffield. Our experience has been that the student only obtains a full grasp of the subject when he has successfully tackled some problems, and we consider that the problems in this book are an essential part of the text; some of the problems provide proofs of statements made in the text. A student benefits most if he is given the minimum of help necessary to enable him to solve the problem. To take a step in this direction we have provided hints to the problems at the end of the book. The student should first try the problems without the hints, but with their help most students should be able to obtain the solutions.
The first five chapters are intended for first year students, since we feel that an early grasp of such concepts as the orbital and the electron-pair bond are necessary for any course in experimental chemistry. The more formal mathematical aspects of the book start in chapter 6 when it has been assumed that the student has received some mathematical training during his first year. These later chapters also assume a knowledge of other branches of chemistry." Authors' preface |
| Cote : |
B-S064 |
| Num_Inv : |
690 |
| Localisation : |
LCC (SdS) |
|  |
Exemplaires(1)
|
690
|
B-S064 |
Texte imprimé |
Bibliothèque |
Livre
|
Disponible |

| Titre : |
Valency and bonding : A natural bond orbital donor-acceptor perspective |
| Type de document : |
texte imprimé |
| Auteurs : |
Frank Weinhold ; Clark R. Landis |
| Editeur : |
Cambridge : Cambridge University Press |
| Année de publication : |
2005 |
| Importance : |
ix, 749 p. |
| Format : |
26 cm. |
| ISBN/ISSN/EAN : |
978-0-521-83128-4 |
| Langues : |
Anglais (eng) |
| Tags : |
CHEMICAL BONDS MOLECULAR STRUCTURE VALENCE |
| Index. décimale : |
EQ -Equipe- |
| Résumé : |
"This textbook develops the foundations of Lewis- and Pauling-like localized structural and hybridization concepts to present the first modernized overview of chemical valency and bonding theory. Directly based on current computational technology, it serves as both a general textbook exposition of modern Lewis, hybridization, and resonance concepts and a comprehensive compilation of NBO-based bonding descriptors--for prototype molecular and supramolecular organic and inorganic species.
* Presents the first modernized overview of chemical valency and bonding theory
* Authors are leaders in the field
* Hundreds of examples for independent reader investigation using computational and analysis tools." |
| Cote : |
LCC/O |
| Num_Inv : |
2959 |
Valency and bonding : A natural bond orbital donor-acceptor perspective [texte imprimé] / Frank Weinhold ; Clark R. Landis . - Cambridge : Cambridge University Press, 2005 . - ix, 749 p. ; 26 cm. ISBN : 978-0-521-83128-4 Langues : Anglais ( eng)
| Tags : |
CHEMICAL BONDS MOLECULAR STRUCTURE VALENCE |
| Index. décimale : |
EQ -Equipe- |
| Résumé : |
"This textbook develops the foundations of Lewis- and Pauling-like localized structural and hybridization concepts to present the first modernized overview of chemical valency and bonding theory. Directly based on current computational technology, it serves as both a general textbook exposition of modern Lewis, hybridization, and resonance concepts and a comprehensive compilation of NBO-based bonding descriptors--for prototype molecular and supramolecular organic and inorganic species.
* Presents the first modernized overview of chemical valency and bonding theory
* Authors are leaders in the field
* Hundreds of examples for independent reader investigation using computational and analysis tools." |
| Cote : |
LCC/O |
| Num_Inv : |
2959 |
|  |
Exemplaires(1)
|
2959
|
LCC/O |
Texte imprimé |
Equipe |
Livre
|
Equipe - Demande préalable Disponible |
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