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Titre : |
Beyond metallocenes: Next-generation polymerization catalysts |
Type de document : |
texte imprimé |
Auteurs : |
Abhimanyu O. Patil, Éditeur scientifique ; Gregory G. Hlatky, Éditeur scientifique |
Editeur : |
Washington : American Chemical Society |
Année de publication : |
2003 |
Collection : |
ACS Symposium Series, ISSN 0097-6156 num. 857  |
Importance : |
249 p. |
ISBN/ISSN/EAN : |
978-0-8412-3838-1 |
Note générale : |
Sponsored by the ACS Division of Polymeric Materials: Science and Engineering |
Langues : |
Anglais (eng) |
Catégories : |
Chimie de coordination, Chimie organométallique, Métaux de transition
|
Tags : |
ALKENES POLYOLEFINS POLYMERIZATION CATALYSIS METALLOCENES POLYMERIZATION CATALYSTS |
Index. décimale : |
B-D |
Résumé : |
"The past 15 years have witnessed tremendous advances in the design and use of organometallic complexes as precatalysts for olefin polymerization. Most recently, an intense search has been started in next-generation single-site catalysts. New approaches have been taken to ligand design.
This research has yielded extraordinary results such as catalysts with activities as high or higher than those of conventional metallocenes, stereospecific and living polymerizations, and amazing new polymer structures such as highly-branched ethylene homopolymers.
This volume presents some of the recent disclosures in this exciting and rapidly expanding field, featuring papers by some of the leading investigators." |
Cote : |
B-D155 (SdS) |
Num_Inv : |
2645 |
Beyond metallocenes: Next-generation polymerization catalysts [texte imprimé] / Abhimanyu O. Patil, Éditeur scientifique ; Gregory G. Hlatky, Éditeur scientifique . - Washington : American Chemical Society, 2003 . - 249 p.. - ( ACS Symposium Series, ISSN 0097-6156; 857) . ISBN : 978-0-8412-3838-1 Sponsored by the ACS Division of Polymeric Materials: Science and Engineering Langues : Anglais ( eng)
Catégories : |
Chimie de coordination, Chimie organométallique, Métaux de transition
|
Tags : |
ALKENES POLYOLEFINS POLYMERIZATION CATALYSIS METALLOCENES POLYMERIZATION CATALYSTS |
Index. décimale : |
B-D |
Résumé : |
"The past 15 years have witnessed tremendous advances in the design and use of organometallic complexes as precatalysts for olefin polymerization. Most recently, an intense search has been started in next-generation single-site catalysts. New approaches have been taken to ligand design.
This research has yielded extraordinary results such as catalysts with activities as high or higher than those of conventional metallocenes, stereospecific and living polymerizations, and amazing new polymer structures such as highly-branched ethylene homopolymers.
This volume presents some of the recent disclosures in this exciting and rapidly expanding field, featuring papers by some of the leading investigators." |
Cote : |
B-D155 (SdS) |
Num_Inv : |
2645 |
|  |
Exemplaires(1)
2645
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B-D155 |
Texte imprimé |
Bibliothèque |
Livre
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Disponible |

Titre : |
Bioinorganic chemistry-II : a symposium co-sponsored by the Division of Inorganic Chemistry and by the Division of Biological Chemistry at the 171st meeting of the American Chemical Society, New York, N.Y., April 7-9, 1976 |
Type de document : |
texte imprimé |
Auteurs : |
K. N. Raymond, Éditeur scientifique |
Mention d'édition : |
1rst |
Editeur : |
Washington : American Chemical Society |
Année de publication : |
1977 |
Collection : |
Advances in Chemistry Series num. 162 |
Importance : |
viii, 448 p. |
ISBN/ISSN/EAN : |
978-0-8412-0359-4 |
Langues : |
Anglais (eng) |
Catégories : |
Biochimie
|
Tags : |
BIOINORGANIC CHEMISTRY-Congresses METALS-Physiological effect |
Note de contenu : |
“Biological transport of iron : Siderophores: Biochemical ecology and mechanism of iron transport in enterobacteria; Kinetically inert complexes of the siderophores in studies of microbial iron transport; Role of iron in the regulation of nutritional immunity; Iron transporting system of mitochondria; Genetically controlled chemical factors involved in absorption and transport of iron by plants; Transport of iron by transferring * Biological electron transport and copper-containing biomolecules: Nonadiabatic electron transfer in oxidation-reduction reactions; Structure and electron transfer reactions of blue copper proteins; Electron transfer reactions of cytochrome c; The mechanism of oxygen reduction in oxidases—studies with laccase and cytochrome oxidase; Electron transfer pathways in blue copper proteins; Mechanism of autoreduction of ferric porphyrins and the activation of coordinated ligands; Iron-sulfur proteins and superoxide dismutases in the biology and evolution of electron transport; Physical and chemical studies of bovine erythrocyte superoxide dismutase; Characterization of the copper(II) site in galactose oxidase; Copper(II)- and copper(III)-peptide complexes; Recent studies on the effect of copper on nucleic acid and nucleoprotein conformation; Bio(in)organic views on flavin-dependent one-electron transfer; Electrochemical and spectroscopic studies of manganese (II, III, IV) complexes as models for the photosynthetic oxygen-evolution reaction * Molybdenum-containing biomolecules: Molybdoenzymes: the role of electrons, protons, and dihydrogen; Molybdenum in enzymes; Uptake and role of molybdenum in nitrogen-fixing bacteria; Reactions of molybdenum with nitrate and naturally produced phenolates. Preparation and X-ray structure of a hydrazine-bridged dinuclear molybdenum complex [Mo(S2CN(C2H5)2)2(CO)2]2N2H4 CH2Cl2 * Index” |
Cote : |
B-F007 (SdS) |
Num_Inv : |
367 |
Bioinorganic chemistry-II : a symposium co-sponsored by the Division of Inorganic Chemistry and by the Division of Biological Chemistry at the 171st meeting of the American Chemical Society, New York, N.Y., April 7-9, 1976 [texte imprimé] / K. N. Raymond, Éditeur scientifique . - 1rst . - Washington : American Chemical Society, 1977 . - viii, 448 p.. - ( Advances in Chemistry Series; 162) . ISBN : 978-0-8412-0359-4 Langues : Anglais ( eng)
Catégories : |
Biochimie
|
Tags : |
BIOINORGANIC CHEMISTRY-Congresses METALS-Physiological effect |
Note de contenu : |
“Biological transport of iron : Siderophores: Biochemical ecology and mechanism of iron transport in enterobacteria; Kinetically inert complexes of the siderophores in studies of microbial iron transport; Role of iron in the regulation of nutritional immunity; Iron transporting system of mitochondria; Genetically controlled chemical factors involved in absorption and transport of iron by plants; Transport of iron by transferring * Biological electron transport and copper-containing biomolecules: Nonadiabatic electron transfer in oxidation-reduction reactions; Structure and electron transfer reactions of blue copper proteins; Electron transfer reactions of cytochrome c; The mechanism of oxygen reduction in oxidases—studies with laccase and cytochrome oxidase; Electron transfer pathways in blue copper proteins; Mechanism of autoreduction of ferric porphyrins and the activation of coordinated ligands; Iron-sulfur proteins and superoxide dismutases in the biology and evolution of electron transport; Physical and chemical studies of bovine erythrocyte superoxide dismutase; Characterization of the copper(II) site in galactose oxidase; Copper(II)- and copper(III)-peptide complexes; Recent studies on the effect of copper on nucleic acid and nucleoprotein conformation; Bio(in)organic views on flavin-dependent one-electron transfer; Electrochemical and spectroscopic studies of manganese (II, III, IV) complexes as models for the photosynthetic oxygen-evolution reaction * Molybdenum-containing biomolecules: Molybdoenzymes: the role of electrons, protons, and dihydrogen; Molybdenum in enzymes; Uptake and role of molybdenum in nitrogen-fixing bacteria; Reactions of molybdenum with nitrate and naturally produced phenolates. Preparation and X-ray structure of a hydrazine-bridged dinuclear molybdenum complex [Mo(S2CN(C2H5)2)2(CO)2]2N2H4 CH2Cl2 * Index” |
Cote : |
B-F007 (SdS) |
Num_Inv : |
367 |
|  |
Exemplaires(1)
367
|
B-F007 |
Texte imprimé |
Bibliothèque |
Livre
|
Disponible |
Titre : |
Borax to boranes |
Type de document : |
texte imprimé |
Auteurs : |
Robert F. Gould, Éditeur scientifique |
Editeur : |
Washington : American Chemical Society |
Année de publication : |
1961 |
Collection : |
Advances in Chemistry Series num. 32 |
Importance : |
viii, 244 p. |
ISBN/ISSN/EAN : |
978-0-8412-0033-3 |
Note générale : |
"A collection of papers comprising the Symposium presented before the Division of Inorganic Chemistry at the 133rd National meeting of the American Chemical Society, San Francisco, California, April 1958, together with three papers from the 135 th ACS Meeting in Boston, Mass., April 1959" |
Langues : |
Anglais (eng) |
Catégories : |
Chimie de coordination, Chimie organométallique, Métaux de transition
|
Tags : |
BORANES BORON COMPOUNDS |
Note de contenu : |
"Pioneer personalities in borane chemistry * Development and present status of the borax industry * Production of ammonium pentaborate and boric oxide from borax * Preparation and chemistry of elementary boron * Structure and polymorphism in elemental boron * High temperature chemistry of the binary compounds of boron * Preparation of diborane
Tetraborane, a review * Mechanisms of isotopic exchanges in the boron hydrides * Kinetics and mechanism for acid-base reactions involving boranes * Kinetics and equilibria in the alkylation of diborane: preliminary report * Explosive oxidation of boranes * Mass spectrometry in boron chemistry * Infrared spectrometry in boron chemistry * Interaction of boranes: a tracer study of the diborane-pentaborane(9) reaction * Unstable intermediates in the pyrolysis of diborane * Conversion of diborane to higher molecular weight boranes in the presence of certain heterogeneous catalysts * Impact of recent developments in boron chemistry on some scientific and engineering problems * Metal boron hydrides * The unusual salts derived from the boron hydrides * Structures of nh3b3h7 and (nh3)2bh2cl * Organoboron compounds: aromatic compounds * Boroxines: aryl and alkoxy derivatives * Synthesis of boron-carbon ring compounds * Borazine chemistry * Research on boron polymers." |
Cote : |
B-D096 (SdS) |
Num_Inv : |
331 |
En ligne : |
http://pubs.acs.org/isbn/9780841200333 |
Borax to boranes [texte imprimé] / Robert F. Gould, Éditeur scientifique . - Washington : American Chemical Society, 1961 . - viii, 244 p.. - ( Advances in Chemistry Series; 32) . ISBN : 978-0-8412-0033-3 "A collection of papers comprising the Symposium presented before the Division of Inorganic Chemistry at the 133rd National meeting of the American Chemical Society, San Francisco, California, April 1958, together with three papers from the 135 th ACS Meeting in Boston, Mass., April 1959" Langues : Anglais ( eng)
Catégories : |
Chimie de coordination, Chimie organométallique, Métaux de transition
|
Tags : |
BORANES BORON COMPOUNDS |
Note de contenu : |
"Pioneer personalities in borane chemistry * Development and present status of the borax industry * Production of ammonium pentaborate and boric oxide from borax * Preparation and chemistry of elementary boron * Structure and polymorphism in elemental boron * High temperature chemistry of the binary compounds of boron * Preparation of diborane
Tetraborane, a review * Mechanisms of isotopic exchanges in the boron hydrides * Kinetics and mechanism for acid-base reactions involving boranes * Kinetics and equilibria in the alkylation of diborane: preliminary report * Explosive oxidation of boranes * Mass spectrometry in boron chemistry * Infrared spectrometry in boron chemistry * Interaction of boranes: a tracer study of the diborane-pentaborane(9) reaction * Unstable intermediates in the pyrolysis of diborane * Conversion of diborane to higher molecular weight boranes in the presence of certain heterogeneous catalysts * Impact of recent developments in boron chemistry on some scientific and engineering problems * Metal boron hydrides * The unusual salts derived from the boron hydrides * Structures of nh3b3h7 and (nh3)2bh2cl * Organoboron compounds: aromatic compounds * Boroxines: aryl and alkoxy derivatives * Synthesis of boron-carbon ring compounds * Borazine chemistry * Research on boron polymers." |
Cote : |
B-D096 (SdS) |
Num_Inv : |
331 |
En ligne : |
http://pubs.acs.org/isbn/9780841200333 |
|  |
Exemplaires(1)
331
|
B-D096 |
Texte imprimé |
Bibliothèque |
Livre
|
Disponible |
Titre : |
Boron-nitrogen chemistry : an international symposium sponsored by U.S. Army Research Office - Durham at Duke University, Durham, N.C., April 23-25, 1963 |
Type de document : |
texte imprimé |
Auteurs : |
Kurt Niedenzu, Éditeur scientifique |
Editeur : |
Washington : American Chemical Society |
Année de publication : |
1964 |
Collection : |
Advances in Chemistry Series num. 42 |
Importance : |
x, 330 p. |
ISBN/ISSN/EAN : |
978-0-8412-2211-3 |
Langues : |
Anglais (eng) |
Catégories : |
Chimie de coordination, Chimie organométallique, Métaux de transition
|
Tags : |
BORON COMPOUNDS NITROGEN COMPOUNDS |
Résumé : |
"A brief look at the papers presented at the symposium illustrates two major advances in boron-nitrogen chemistry which have contributed much toward influencing the growth of research in this field. Since A. W. Laubengayer's synthesis of B-trichloroborazine (1955), the practice of using high vacuum techniques has been partially supplanted by more classical approaches, and the utilization of spectroscopy as a tool for explaining both structures and mechanisms has been stimulated by the investigations of J. Goubeau and his school. New instrumental methods - for instance, the applications of NMR spectroscopy - have been found extremely helpful in exploring former postulations. Advances in preparation are illustrated by the fact that ten years ago some two dozen substituted borazines were known, whereas today more than two hundred such compounds have been described in the literature. Incorporation of the B-N grouping in aromatic nuclei gave access to a whole new area of boron-nitrogen derivatives and the interest of the theoretician has been attracted by the evolution of new and exciting structures and reactions. It is obvious from reading the symposium papers that a fruitful collaboration is developing in the area of boronnitrogen chemistry." |
Cote : |
B-D099 (SdS) |
Num_Inv : |
334 |
En ligne : |
http://pubs.acs.org/doi/book/10.1021/ba-1964-0042 |
Boron-nitrogen chemistry : an international symposium sponsored by U.S. Army Research Office - Durham at Duke University, Durham, N.C., April 23-25, 1963 [texte imprimé] / Kurt Niedenzu, Éditeur scientifique . - Washington : American Chemical Society, 1964 . - x, 330 p.. - ( Advances in Chemistry Series; 42) . ISBN : 978-0-8412-2211-3 Langues : Anglais ( eng)
Catégories : |
Chimie de coordination, Chimie organométallique, Métaux de transition
|
Tags : |
BORON COMPOUNDS NITROGEN COMPOUNDS |
Résumé : |
"A brief look at the papers presented at the symposium illustrates two major advances in boron-nitrogen chemistry which have contributed much toward influencing the growth of research in this field. Since A. W. Laubengayer's synthesis of B-trichloroborazine (1955), the practice of using high vacuum techniques has been partially supplanted by more classical approaches, and the utilization of spectroscopy as a tool for explaining both structures and mechanisms has been stimulated by the investigations of J. Goubeau and his school. New instrumental methods - for instance, the applications of NMR spectroscopy - have been found extremely helpful in exploring former postulations. Advances in preparation are illustrated by the fact that ten years ago some two dozen substituted borazines were known, whereas today more than two hundred such compounds have been described in the literature. Incorporation of the B-N grouping in aromatic nuclei gave access to a whole new area of boron-nitrogen derivatives and the interest of the theoretician has been attracted by the evolution of new and exciting structures and reactions. It is obvious from reading the symposium papers that a fruitful collaboration is developing in the area of boronnitrogen chemistry." |
Cote : |
B-D099 (SdS) |
Num_Inv : |
334 |
En ligne : |
http://pubs.acs.org/doi/book/10.1021/ba-1964-0042 |
|  |
Exemplaires(1)
334
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B-D099 |
Texte imprimé |
Bibliothèque |
Livre
|
Disponible |

Exemplaires(1)
2691
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B-E028 |
Texte imprimé |
Bibliothèque |
Livre
|
Disponible |

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